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Titolo:
Structure, solvatochromism, and solvation of trans-[Co-III(cyclam)(NCS)(2)](NCS) and the structure of [Co-II(Me(4)cyclam)(NCS)](2)[Co(NCS)(4)]MeOH
Autore:
Burgess, J; Fawcett, J; Haines, RI; Singh, K; Russell, DR;
Indirizzi:
Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England Univ Leicester Leicester Leics England LE1 7RH er LE1 7RH, Leics, England
Titolo Testata:
TRANSITION METAL CHEMISTRY
fascicolo: 3, volume: 24, anno: 1999,
pagine: 355 - 361
SICI:
0340-4285(199906)24:3<355:SSASOT>2.0.ZU;2-I
Fonte:
ISI
Lingua:
ENG
Soggetto:
TRANSFER CHEMICAL-POTENTIALS; AQUEOUS METHANOL; CRYSTAL-STRUCTURE; SOLVENT POLARITY; COMPLEXES; IRON(II); WATER; CHROMIUM(III); SOLUBILITIES; COBALT(III);
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
38
Recensione:
Indirizzi per estratti:
Indirizzo: Fawcett, J Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England Univ Leicester Leicester Leics England LE1 7RH Leics, England
Citazione:
J. Burgess et al., "Structure, solvatochromism, and solvation of trans-[Co-III(cyclam)(NCS)(2)](NCS) and the structure of [Co-II(Me(4)cyclam)(NCS)](2)[Co(NCS)(4)]MeOH", TRANSIT MET, 24(3), 1999, pp. 355-361

Abstract

The structures of trans-[Co-III(cyclam)(NCS)(2)](NCS) and of [Co-II(Me(4)cyclam)(NCS)](2)[Co(NCS)(4)]. MeOH have been established by X-ray diffraction methods. The solvatochromic behavior of the trans-[Co(cyclam)(NCS)(2)](+)cation in several binary aqueous solvent mixtures is reported. Transfer chemical potentials for this complex from H2O into MeOH-H2O mixtures have been established from solubility measurements on its thiocyanate salt. The solvatochromic behavior of this cation is discussed in the context of other solvatochromic inorganic complexes; its transfer chemical potentials are discussed in relation to those of other cobalt(III) complexes.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 06/04/20 alle ore 21:47:07