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Titolo:
THE CHEMISTRY OF 1,3,5-TRIAZACYCLOHEXANE COMPLEXES, 7 - SYNTHESIS ANDSTRUCTURE DETERMINATION OF ,5-TRIAZACYCLOHEXANE))ZINC(II)-HEXAFLUOROPHOSPHATE
Autore:
HAUFE M; KOHN RD; KOCIOKKOHN G; FILIPPOU AC;
Indirizzi:
TECH UNIV BERLIN,INST ANORGAN & ANALYT CHEM & LEHREBILDUNG CHEM,SEKR C2,STR 17 JUNI 135 D-10623 BERLIN GERMANY TECH UNIV BERLIN,INST ANORGAN & ANALYT CHEM & LEHREBILDUNG CHEM D-10623 BERLIN GERMANY HUMBOLDT UNIV,INST ANORGAN & ALLGEMEINE CHEM D-10115 BERLIN GERMANY
Titolo Testata:
INORGANIC CHEMISTRY COMMUNICATIONS
fascicolo: 7, volume: 1, anno: 1998,
pagine: 263 - 266
SICI:
1387-7003(1998)1:7<263:TCO1C7>2.0.ZU;2-X
Fonte:
ISI
Lingua:
ENG
Keywords:
CRYSTAL STRUCTURES; ZINC COMPLEXES; ALKYL COMPLEXES; TRIAZACYCLOHEXANE COMPLEXES;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
11
Recensione:
Indirizzi per estratti:
Citazione:
M. Haufe et al., "THE CHEMISTRY OF 1,3,5-TRIAZACYCLOHEXANE COMPLEXES, 7 - SYNTHESIS ANDSTRUCTURE DETERMINATION OF ,5-TRIAZACYCLOHEXANE))ZINC(II)-HEXAFLUOROPHOSPHATE", INORGANIC CHEMISTRY COMMUNICATIONS, 1(7), 1998, pp. 263-266

Abstract

Diethylzinc reacts with the hydrohexafluorophospate salt of 1,3,5-tribenzyl-1,3,5-triazacyclohexane (Bz,TAC) to give the cationic complex [(Bz(3)TAC)Zn(Et)] (PF6). The crystal and molecular structure of the compound has been determined by X-ray diffraction. This structure agreeswith the structure previously predicted by NOESY spectroscopy for therelated compounds [(FBz(3)TAC)Zn(Et)](BF4) (FBz= p-fluorobenzyl) and [{(s-PhMeCH)(3)TAC}Zn(Et)]([BF4). The differences can be explained by close PF6--Zn contact in the solid state. (C) 1998 Elsevier Science S.A. All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 24/11/20 alle ore 07:35:31