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Titolo: THE PREPARATION AND X-RAY CRYSTAL-STRUCTURE OF [CO(PH2SNH)(6)]CL-2, AHOMOLEPTIC SULFIMIDE COMPLEX EXHIBITING COOPERATIVE, DIRECTED HYDROGEN-BONDS BETWEEN CATIONS AND ANIONS
Autore: KELLY PF; SLAWIN AMZ; WARING KW;
- Indirizzi:
- LOUGHBOROUGH UNIV TECHNOL,DEPT CHEM LOUGHBOROUGH LE11 3TU LEICS ENGLAND
- Titolo Testata:
- INORGANIC CHEMISTRY COMMUNICATIONS
fascicolo: 7,
volume: 1,
anno: 1998,
pagine: 249 - 250
- SICI:
- 1387-7003(1998)1:7<249:TPAXCO>2.0.ZU;2-9
- Fonte:
- ISI
- Lingua:
- ENG
- Keywords:
- HOMOLEPTIC SULFIMIDE COMPLEXES; CRYSTAL STRUCTURES; OCTAHEDRAL COORDINATION GEOMETRY; COPPER(II) COMPLEXES;
- Tipo documento:
- Article
- Natura:
- Periodico
- Settore Disciplinare:
- Science Citation Index Expanded
- Citazioni:
- 4
- Recensione:
- Indirizzi per estratti:
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- Citazione:
- P.F. Kelly et al., "THE PREPARATION AND X-RAY CRYSTAL-STRUCTURE OF [CO(PH2SNH)(6)]CL-2, AHOMOLEPTIC SULFIMIDE COMPLEX EXHIBITING COOPERATIVE, DIRECTED HYDROGEN-BONDS BETWEEN CATIONS AND ANIONS", INORGANIC CHEMISTRY COMMUNICATIONS, 1(7), 1998, pp. 249-250
Abstract
At ambient temperatures, in CH3CN, a six-fold excess of S,S-diphenylsulfimide (1) reacts with anhydrous CoCl2 to give [Co(Ph2SNH)(6)] Cl-2 (2), the first example of a homoleptic sulfimide complex. In addition to the expected octahedral coordination geometry, X-ray crystallography reveals significant directed hydrogen bonding from the N-H groups onthe ligands to the chlorides. Thus the three N-H bonds on opposite coordination faces act as cooperative hydrogen-bonding pockets for the chloride counterions. (C) 1998 Elsevier Science S.A. All rights reserved.
ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 24/11/20 alle ore 14:40:43