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Titolo:
THE PREPARATION AND X-RAY CRYSTAL-STRUCTURE OF [CO(PH2SNH)(6)]CL-2, AHOMOLEPTIC SULFIMIDE COMPLEX EXHIBITING COOPERATIVE, DIRECTED HYDROGEN-BONDS BETWEEN CATIONS AND ANIONS
Autore:
KELLY PF; SLAWIN AMZ; WARING KW;
Indirizzi:
LOUGHBOROUGH UNIV TECHNOL,DEPT CHEM LOUGHBOROUGH LE11 3TU LEICS ENGLAND
Titolo Testata:
INORGANIC CHEMISTRY COMMUNICATIONS
fascicolo: 7, volume: 1, anno: 1998,
pagine: 249 - 250
SICI:
1387-7003(1998)1:7<249:TPAXCO>2.0.ZU;2-9
Fonte:
ISI
Lingua:
ENG
Keywords:
HOMOLEPTIC SULFIMIDE COMPLEXES; CRYSTAL STRUCTURES; OCTAHEDRAL COORDINATION GEOMETRY; COPPER(II) COMPLEXES;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
4
Recensione:
Indirizzi per estratti:
Citazione:
P.F. Kelly et al., "THE PREPARATION AND X-RAY CRYSTAL-STRUCTURE OF [CO(PH2SNH)(6)]CL-2, AHOMOLEPTIC SULFIMIDE COMPLEX EXHIBITING COOPERATIVE, DIRECTED HYDROGEN-BONDS BETWEEN CATIONS AND ANIONS", INORGANIC CHEMISTRY COMMUNICATIONS, 1(7), 1998, pp. 249-250

Abstract

At ambient temperatures, in CH3CN, a six-fold excess of S,S-diphenylsulfimide (1) reacts with anhydrous CoCl2 to give [Co(Ph2SNH)(6)] Cl-2 (2), the first example of a homoleptic sulfimide complex. In addition to the expected octahedral coordination geometry, X-ray crystallography reveals significant directed hydrogen bonding from the N-H groups onthe ligands to the chlorides. Thus the three N-H bonds on opposite coordination faces act as cooperative hydrogen-bonding pockets for the chloride counterions. (C) 1998 Elsevier Science S.A. All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 24/11/20 alle ore 14:40:43