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Titolo:
STRUCTURE OF O(1,4,7,11,14-PENTAAZACYCLOHEPTADECANE)COBALT(III) CHLORIDE PERCHLORATE
Autore:
TAHIROV TH; LU TH; CHEN BH; LAI CY; CHUNG CS;
Indirizzi:
NATL TSING HUA UNIV,DEPT PHYS HSINCHU 300 TAIWAN NATL TSING HUA UNIV,DEPT CHEM HSINCHU 300 TAIWAN
Titolo Testata:
Acta crystallographica. Section C, Crystal structure communications
, volume: 49, anno: 1993,
parte:, 11
pagine: 1910 - 1912
SICI:
0108-2701(1993)49:<1910:SOOC>2.0.ZU;2-2
Fonte:
ISI
Lingua:
ENG
Soggetto:
COMPLEXES;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
6
Recensione:
Indirizzi per estratti:
Citazione:
T.H. Tahirov et al., "STRUCTURE OF O(1,4,7,11,14-PENTAAZACYCLOHEPTADECANE)COBALT(III) CHLORIDE PERCHLORATE", Acta crystallographica. Section C, Crystal structure communications, 49, 1993, pp. 1910-1912

Abstract

The coordination geometry about the Co-III ion in the title compound,)-1,4,7,11,14-pentaazacycloheptadecane]cobalt(III) chloride perchlorate, is distorted square bipyramidal with four tetraamine N atoms equatorial and a Cl and an N atom axial. The equatorial N atoms are nearly coplanar with the largest deviation from the least-squares plane of 0.018 Angstrom; the deviation of the Co-III ion from the plane is 0.039 Angstrom. Both six-membered rings are in chair forms and all three five-membered rings in gauche forms. The configuration of the chiral N centres is (1RS, 7SR, 11SR, 14RS).

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 09/07/20 alle ore 14:23:06