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Titolo:
X-RAY-ABSORPTION FINE-STRUCTURE STUDY OF THE BOUND-STATE ELECTRONIC-TRANSITIONS AT THE VANADIUM-K AND VANADIUM-L EDGES IN LOW-SYMMETRY, MOLECULAR, VANADIUM-(IV) AND VANADIUM-(V) COMPLEXES WITH OXYOXIME AND OXYOXIMATE LIGANDS
Autore:
COLLISON D; GARNER CD; GRIGG J; MCGRATH CM; MOSSELMANS JFW; PIDCOCK E; ROPER MD; SEDDON JMW; SINN E; TASKER PA; THORNTON G; WALSH JF; YOUNG NA;
Indirizzi:
UNIV MANCHESTER,DEPT CHEM,OXFORD RD MANCHESTER M13 9PL LANCS ENGLAND UNIV HULL,DEPT CHEM KINGSTON HULL HU6 7RX N HUMBERSIDE ENGLAND DARESBURY LAB,CCLRC WARRINGTON WA4 4AD CHESHIRE ENGLAND ZENECA SPECIALTIES RES CTR MANCHESTER M9 3DA LANCS ENGLAND UNIV EDINBURGH,DEPT CHEM EDINBURGH EH9 3JJ MIDLOTHIAN SCOTLAND UNIV MANCHESTER,DEPT CHEM,IRC SURFACE SCI MANCHESTER M13 9PL LANCS ENGLAND
Titolo Testata:
Journal of the Chemical Society. Dalton transactions
fascicolo: 13, , anno: 1998,
pagine: 2199 - 2204
SICI:
0300-9246(1998):13<2199:XFSOTB>2.0.ZU;2-N
Fonte:
ISI
Lingua:
ENG
Soggetto:
COORDINATION-COMPOUNDS; METAL COMPOUNDS; SPECTROSCOPY; SPECTRA; OXIDES; DARESBURY;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
33
Recensione:
Indirizzi per estratti:
Citazione:
D. Collison et al., "X-RAY-ABSORPTION FINE-STRUCTURE STUDY OF THE BOUND-STATE ELECTRONIC-TRANSITIONS AT THE VANADIUM-K AND VANADIUM-L EDGES IN LOW-SYMMETRY, MOLECULAR, VANADIUM-(IV) AND VANADIUM-(V) COMPLEXES WITH OXYOXIME AND OXYOXIMATE LIGANDS", Journal of the Chemical Society. Dalton transactions, (13), 1998, pp. 2199-2204

Abstract

A combination of vanadium K- and L-edge XAFS has been used to characterise a series of monomeric oxovanadium(Iv), monomeric dioxovanadium(v) and dimeric oxovanadium(v) complexes with oxyoxime and oxyoximate ligands. The K- and L-edge spectra confirm the presence of VV in the dimeric species and the L-edge spectra have been used to discriminate between six-co-ordinate V-N-O-V bridged oxovanadium(v) dimers and seven-co-ordinate phenolate bridged oxovanadium(v) dimers containing eta(2)-N-O groups.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 28/11/20 alle ore 15:39:25