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Titolo:
ELECTROCHEMICAL DOPING OF TETRAMETHYLAMMONIUM IONS INTO C-60 FILM
Autore:
WANG WJ; CHIU HS; LIN SS; CHANG CS; CHUANG KS;
Indirizzi:
TAMKANG UNIV,DEPT CHEM TAMSUI 25137 TAIWAN
Titolo Testata:
Fullerene science and technology
fascicolo: 4, volume: 6, anno: 1998,
pagine: 681 - 687
SICI:
1064-122X(1998)6:4<681:EDOTII>2.0.ZU;2-H
Fonte:
ISI
Lingua:
ENG
Soggetto:
CYCLIC VOLTAMMETRY; FULLERENE FILMS; BUCKMINSTERFULLERENE;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Science Citation Index Expanded
Science Citation Index Expanded
Citazioni:
10
Recensione:
Indirizzi per estratti:
Citazione:
W.J. Wang et al., "ELECTROCHEMICAL DOPING OF TETRAMETHYLAMMONIUM IONS INTO C-60 FILM", Fullerene science and technology, 6(4), 1998, pp. 681-687

Abstract

The electrochemical properties of C-60 films were studied by cyclic voltammetry and electrochemical quartz crystal microbalance technique in organic electrolyte solution. Tetramethylammonium perchlorate was used as a supporting electrolyte in acetonitrile solution. Thin films are prepared by solvent quickly evaporated method on a preheated glassy carbon electrode. The electrochemical response of C-60 films is consistent with a reduction mechanism that is domina:ed by ion transport to form contact ion pair. In the proposed mechanism, swelling of the filmwith solvent and intercalation of cations into the film proceed parallelly. The stability of the film with respect to successive redox cycles was also interpreted.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 10/07/20 alle ore 12:23:46