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Titolo:
REACTION OF 4-PHENYLBUT-3-EN-2-ONE WITH CYANOACETAMIDE IN 2-1 RATIO
Autore:
OCALLAGHAN CN; MCMURRY TBH; CARDIN CJ; WILCOCK DJ;
Indirizzi:
UNIV DUBLIN TRINITY COLL,DEPT CHEM,CHEM LAB DUBLIN 2 IRELAND
Titolo Testata:
Journal of the Chemical Society. Perkin transactions. I
fascicolo: 20, , anno: 1993,
pagine: 2479 - 2486
SICI:
0300-922X(1993):20<2479:RO4WCI>2.0.ZU;2-3
Fonte:
ISI
Lingua:
ENG
Soggetto:
REVERSE-TRANSCRIPTASE INHIBITORS; 2-PYRIDINONE DERIVATIVES; ALPHA,BETA-UNSATURATED KETONES; ANALOGS; MALONONITRILE;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
31
Recensione:
Indirizzi per estratti:
Citazione:
C.N. Ocallaghan et al., "REACTION OF 4-PHENYLBUT-3-EN-2-ONE WITH CYANOACETAMIDE IN 2-1 RATIO", Journal of the Chemical Society. Perkin transactions. I, (20), 1993, pp. 2479-2486

Abstract

The reaction of 4-phenylbut-3-en-2-one with cyanoacetamide is not confined to a 1:1 reaction [which results in formation of 3-cyano-6-methyl-4-phenylpyridin-2(1H)-one], The reaction of 2 mole equivalents of 4-phenylbut-3-en-2-one with one of cyanoacetamide also takes place, the products being hylene-8,9-diphenyl-3-azabicyclo[3.3.1]nonan-2-one and henylbutyl)-4-phenyl-3,4-dihydropyridin-2(1H)-one. The latter compoundcyclises in acid medium to form ethyl-5,8-diphenyl-2-azabicyclo[2.2.2]octan-3-one. X-Ray crystal structures of the 3-azabicyclo[3.3.1]nonan-2-one and the 3-azabicyclo[2.2.2]octan-2-one derivatives are described.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 29/11/20 alle ore 02:17:50