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Titolo:
CYANONITROSYLMETALLATES AS POTENTIAL NO-DONORS
Autore:
OSZAJCA J; STOCHEL G; WASIELEWSKA E; STASICKA Z; GRYGLEWSKI RJ; JAKUBOWSKI A; CIESLIK K;
Indirizzi:
JAGIELLONIAN UNIV,DEPT INORGAN CHEM,INGARDENA 3 PL-30060 KRAKOW POLAND JAGIELLONIAN UNIV,DEPT INORGAN CHEM PL-30060 KRAKOW POLAND JAGIELLONIAN UNIV,COLL MED,DEPT PHARMACOL PL-31531 KRAKOW POLAND
Titolo Testata:
Journal of inorganic biochemistry
fascicolo: 1-2, volume: 69, anno: 1998,
pagine: 121 - 127
SICI:
0162-0134(1998)69:1-2<121:CAPN>2.0.ZU;2-Q
Fonte:
ISI
Lingua:
ENG
Soggetto:
TRANSITION-METAL COMPOUNDS; NITRIC-OXIDE SYNTHASE; NITROSYL COMPLEXES; AQUEOUS-SOLUTION; NITROPRUSSIDE; REACTIVITY; SINDO; IONS; PENTACYANONITROSYLFERRATE(2-); NITROSYLPENTACYANOFERRATE(II);
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Science Citation Index Expanded
Citazioni:
63
Recensione:
Indirizzi per estratti:
Citazione:
J. Oszajca et al., "CYANONITROSYLMETALLATES AS POTENTIAL NO-DONORS", Journal of inorganic biochemistry, 69(1-2), 1998, pp. 121-127

Abstract

The [M(CN)(x)NOy](n-) complexes (where M = Cr(I), Mn(I), Mn(II), Fe(I), Fe(II), Fe(III)) were studied as potential NO-donors using both pharmacological and theoretical semi-empirical methods. Only iron complexes appeared to be pharmacologically active. The quantum chemical calculations indicated that these complexes have the highest predispositionto undergo a nucleophilic attack followed by the NO+ release. The results allowed us to interpret the metabolism of the [M(CN)(x)NOy](n-) complexes in terms of the NO+-donation. (C) 1998 Elsevier Science Inc. All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 25/09/20 alle ore 22:16:00