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Titolo:
METAL ADDUCTS OF DISELENIUM DINITRIDE
Autore:
KELLY PF; SLAWIN AMZ;
Indirizzi:
LOUGHBOROUGH UNIV TECHNOL,DEPT CHEM LOUGHBOROUGH LE11 3TU LEICS ENGLAND
Titolo Testata:
Phosphorus, sulfur and silicon and the related elements
, volume: 125, anno: 1997,
pagine: 437 - 440
SICI:
1042-6507(1997)125:<437:MAODD>2.0.ZU;2-1
Fonte:
ISI
Lingua:
ENG
Keywords:
SELENIUM; NITRIDE; ADDUCTS; PALLADIUM; ALUMINUM;
Tipo documento:
Article
Natura:
Periodico
Citazioni:
3
Recensione:
Indirizzi per estratti:
Citazione:
P.F. Kelly e A.M.Z. Slawin, "METAL ADDUCTS OF DISELENIUM DINITRIDE", Phosphorus, sulfur and silicon and the related elements, 125, 1997, pp. 437-440

Abstract

Adducts of diselenium dinitride, a species as yet unknown in the freestate, may be prepared with either palladium or aluminium as the metal centre. Thus salts of [Pd2X6](2-) (X = Cl or Br) react with Se4N4 at100 degrees C in CH2Cl2 to give [Pd2X6(Se2N2)](2-) while A1X(3) reacts with the same reagent, at ambient temperatures in CH2X2 to give [(A1X(3))(2)(Se2N2)]. When X = Cl in the latter case the product cannot beobtained in pure crystalline form; here we present IR data which confirms the presence of the neutral Se2N2 unit.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 04/12/20 alle ore 19:18:58