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Titolo:
P-BLOCK METALLOCENES - THE OTHER SIDE OF THE COIN
Autore:
BESWICK MA; PALMER JS; WRIGHT DS;
Indirizzi:
UNIV CAMBRIDGE,DEPT CHEM,LENSFIELD RD CAMBRIDGE CB2 1EW ENGLAND
Titolo Testata:
Chemical Society reviews
fascicolo: 3, volume: 27, anno: 1998,
pagine: 225 - 232
SICI:
0306-0012(1998)27:3<225:PM-TOS>2.0.ZU;2-S
Fonte:
ISI
Lingua:
ENG
Soggetto:
ELEMENTS; CRYSTAL;
Tipo documento:
Review
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
29
Recensione:
Indirizzi per estratti:
Citazione:
M.A. Beswick et al., "P-BLOCK METALLOCENES - THE OTHER SIDE OF THE COIN", Chemical Society reviews, 27(3), 1998, pp. 225-232

Abstract

Although transition metal metallocenes {such as ferrocene, [(C5H5)(2)Fe]} have been a cornerstone in the development of modern organometallic chemistry and continue to be a focus for chemical and structural studies, in comparison the chemistry of the main group metal counterparts has remained relatively undeveloped. The recent resurgence of interest in p-block (Groups 13-15) metallocenes in particular has given fresh insights into the structural preferences, bonding requirements and reactivity of these under-publicised species, which in many ways represent 'the other side of the coin'. The more varied (ionic and covalent)character of the metal-ligand bonds and the less restricted electronic requirements of p-block metals leads to greater structural diversityand radically different reactivity than is found for the transition metal relatives. This short review focuses on the remarkable range of p-block complexes that has so far been uncovered and attempts to unravel some of the electronic and structural trends in these species.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 10/04/20 alle ore 02:33:41