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Titolo:
Molecular structure of [CpFe(CO)(2)](3)In
Autore:
Borovik, AS; Bott, SG; Barron, AR;
Indirizzi:
Univ Houston, Dept Chem, Houston, TX 77204 USA Univ Houston Houston TX USA 77204 uston, Dept Chem, Houston, TX 77204 USA Rice Univ, Dept Chem, Houston, TX 77005 USA Rice Univ Houston TX USA 77005 ice Univ, Dept Chem, Houston, TX 77005 USA
Titolo Testata:
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
fascicolo: 11, volume: 28, anno: 1998,
pagine: 835 - 838
SICI:
1074-1542(199811)28:11<835:MSO[>2.0.ZU;2-0
Fonte:
ISI
Lingua:
ENG
Soggetto:
COMPLEXES; INDIUM;
Keywords:
indium; iron; cyclopentadienyl; carbonyl;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
13
Recensione:
Indirizzi per estratti:
Indirizzo: Bott, SG Univ Houston, Dept Chem, Univ Pk, Houston, TX 77204 USA Univ Houston Univ Pk Houston TX USA 77204 , Houston, TX 77204 USA
Citazione:
A.S. Borovik et al., "Molecular structure of [CpFe(CO)(2)](3)In", J CHEM CRYS, 28(11), 1998, pp. 835-838

Abstract

The molecular structure of [CpFe(Co)(2)](3)In (Cp=eta(5)-C5H5) has been determined and contains a planar, three-coordinate indium center bound to three CpFe(CO)(2) moieties by unsupported In-Fe bonds. The orientation of the CpFe(CO)(2) units relative to the Fe3In plane precludes pi-type interactionbetween iron and indium, while comparison with the isostructural gallium analog suggests the orientation of the CpFe(CO)(2) units is controlled by the size of the central atom and the inter-ligand steric repulsion. Crystal data: monoclinic, monoclinic, C2/c, a = 26.911(5), b = 10.838(2), c = 16.474(3)Angstrom, beta = 111.63(3)degrees, V = 4465(2)Angstrom(3) and, Z = 8.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 23/09/20 alle ore 12:57:15