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Titolo:
OXIDATION OF AMINO ESTERS TO IMINE COMPLEXES WITH CHIRAL HIGH-VALENT OXORUTHENIUM PORPHYRINS
Autore:
MORICE C; LEMAUX P; MOINET C; SIMONNEAUX G;
Indirizzi:
UNIV RENNES 1,LAB CHIM ORGANOMET & BIOL F-35042 RENNES FRANCE UNIV RENNES 1,LAB CHIM ORGANOMET & BIOL F-35042 RENNES FRANCE UNIV RENNES 1,LAB ELECTROCHIM & ORGANOMET,CNRS,UMR 6509 F-35042 RENNES FRANCE
Titolo Testata:
Inorganica Chimica Acta
fascicolo: 1-2, volume: 273, anno: 1998,
pagine: 142 - 150
SICI:
0020-1693(1998)273:1-2<142:OOAETI>2.0.ZU;2-1
Fonte:
ISI
Lingua:
ENG
Soggetto:
RUTHENIUM PORPHYRINS; RACEMIC PHOSPHINES; CRYSTAL-STRUCTURE; REDOX CHEMISTRY; ACIDS; DEHYDROGENATION; ION; OCTAETHYLPORPHYRIN; SPECTROSCOPY; DERIVATIVES;
Keywords:
OXIDATION; RUTHENIUM COMPLEXES; OXO COMPLEXES; AMINO ESTER COMPLEXES; IMINO ESTERS;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
47
Recensione:
Indirizzi per estratti:
Citazione:
C. Morice et al., "OXIDATION OF AMINO ESTERS TO IMINE COMPLEXES WITH CHIRAL HIGH-VALENT OXORUTHENIUM PORPHYRINS", Inorganica Chimica Acta, 273(1-2), 1998, pp. 142-150

Abstract

The chemical oxidation of amino esters by high valent oxoruthenium porphyrins to give mixed ligated imino ester/amino ester ruthenium( II) porphyrin complexes is described. The same complexes were also obtained by anodic oxidation at a constant potential of the corresponding bis(amino ester) ruthenium(II) porphyrins. The electrochemical data were found consistent with a mechanism involving a Ru(IV) intermediate formed by disproportionation of a Ru(III) species. (C) 1998 Elsevier Science S.A. All rights reserved.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 10/07/20 alle ore 11:28:33