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Titolo:
ELUCIDATION OF THE MECHANISM OF ALKENE EPOXIDATION BY HYDROGEN-PEROXIDE CATALYZED BY TITANOSILICATES - A COMPUTATIONAL STUDY
Autore:
TANTANAK D; VINCENT MA; HILLIER IH;
Indirizzi:
UNIV MANCHESTER,DEPT CHEM,OXFORD RD MANCHESTER M13 9PL LANCS ENGLAND UNIV MANCHESTER,DEPT CHEM MANCHESTER M13 9PL LANCS ENGLAND
Titolo Testata:
Chemical communications
fascicolo: 9, , anno: 1998,
pagine: 1031 - 1032
SICI:
1359-7345(1998):9<1031:EOTMOA>2.0.ZU;2-9
Fonte:
ISI
Lingua:
ENG
Soggetto:
BRONSTED ACID SITES; AB-INITIO; ELECTRON CORRELATION; TITANIUM SILICALITE; ZEOLITE CATALYSTS; OXIDATION; METHANOL;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
14
Recensione:
Indirizzi per estratti:
Citazione:
D. Tantanak et al., "ELUCIDATION OF THE MECHANISM OF ALKENE EPOXIDATION BY HYDROGEN-PEROXIDE CATALYZED BY TITANOSILICATES - A COMPUTATIONAL STUDY", Chemical communications, (9), 1998, pp. 1031-1032

Abstract

Calculated transition states for alkene epoxidation by hydrogen peroxide, catalysed by titanosilicates, predict that it is the oxygen atom of the titanium(IV)-hydroperoxide intermediate closer to the metal centre which attacks the alkene.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 04/12/20 alle ore 05:52:29