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Titolo:
DIIODOTETRAKIS[TRIS(DIMETHYLAMINO)-PHOSPHINE OXIDE-O]BISMUTH(III) PENTAIODIDE, [BII2(OP(NME2)(3))(4)][I-5]
Autore:
FARRUGIA LJ; NORMAN NC; PICKETT NL;
Indirizzi:
UNIV GLASGOW,DEPT CHEM GLASGOW G12 8QQ LANARK SCOTLAND UNIV BRISTOL,SCH CHEM BRISTOL BS8 1TS AVON ENGLAND UNIV NEWCASTLE UPON TYNE,DEPT CHEM NEWCASTLE TYNE NE1 7RU TYNE & WEARENGLAND
Titolo Testata:
Acta crystallographica. Section C, Crystal structure communications
, volume: 54, anno: 1998,
parte:, 4
pagine: 476 - 479
SICI:
0108-2701(1998)54:<476:DOP>2.0.ZU;2-O
Fonte:
ISI
Lingua:
ENG
Soggetto:
COMPLEXES; CRYSTAL;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
15
Recensione:
Indirizzi per estratti:
Citazione:
L.J. Farrugia et al., "DIIODOTETRAKIS[TRIS(DIMETHYLAMINO)-PHOSPHINE OXIDE-O]BISMUTH(III) PENTAIODIDE, [BII2(OP(NME2)(3))(4)][I-5]", Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 476-479

Abstract

The title compound, [BiI2(C6H18N3OP)(4)](I-5), contains the pseudo-octahedral Bi-III cation [BiI2{OP(NMe2)(3)}(4)](+), which has crystallographic (4) over bar symmetry, and trans iodide ligands. The central I atom of the disordered [I-5](-) anion is also situated on a site of (4) over bar symmetry and the atoms of this anion form an infinite three-dimensional network, resulting in a 'cage'-type structure. The cations are situated within the 'cage' cavities.

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Documento generato il 01/10/20 alle ore 16:10:46