Catalogo Articoli (Spogli Riviste)

OPAC HELP

Titolo:
TRIPLE-DECKER COMPLEXES .12. TRIPLE-DECKER COMPLEXES WITH BRIDGING BORATABENZENE LIGANDS - SYNTHESES, STRUCTURES OF [(MU-C(5)H(5)BME)(FECP-ASTERISK)(2)]PF6 AND OF [(MU-C(5)H(5)BME)(RH(COD))(2)]CF3SO3, AND BORATABENZENE TRANSFER-REACTIONS
Autore:
HERBERICH GE; ENGLERT U; GANTER B; LAMERTZ C;
Indirizzi:
RHEIN WESTFAL TH AACHEN,INST ANORGAN CHEM D-52056 AACHEN GERMANY
Titolo Testata:
Organometallics
fascicolo: 24, volume: 15, anno: 1996,
pagine: 5236 - 5241
SICI:
0276-7333(1996)15:24<5236:TC.TCW>2.0.ZU;2-Z
Fonte:
ISI
Lingua:
ENG
Soggetto:
CYCLOPENTADIENYL TRANSFER-REACTIONS; BORABENZENE DERIVATIVES; SANDWICH COMPOUNDS; BENZENE-RING;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Science Citation Index Expanded
Citazioni:
40
Recensione:
Indirizzi per estratti:
Citazione:
G.E. Herberich et al., "TRIPLE-DECKER COMPLEXES .12. TRIPLE-DECKER COMPLEXES WITH BRIDGING BORATABENZENE LIGANDS - SYNTHESES, STRUCTURES OF [(MU-C(5)H(5)BME)(FECP-ASTERISK)(2)]PF6 AND OF [(MU-C(5)H(5)BME)(RH(COD))(2)]CF3SO3, AND BORATABENZENE TRANSFER-REACTIONS", Organometallics, 15(24), 1996, pp. 5236-5241

Abstract

The orange complex CpFe(C(5)H(5)BMe) (1a) was synthesized from [Cp*Fe(NCMe)(3)]PF6 and Li(C(5)H(5)BMe) in 91% yield. Electrophilic stacking reactions with metalloelectrophiles gave the triple-decker salts [(mu-C(5)H(5)BMe)(FeCp)(2)]PF6 (4), [(mu-C(5)H(5)BMe)(FeCp*)(RuCp*)]CF3SO3 (5), and [(mu-C(5)H(5)BMe)(FeCp)(MCp**)](CF3SO3)(2) with M = Rh (for 6) and M = Ir (for 7). Electrophilic stacking of Rh(C(5)H(5)BMe)(COD) (8) with [(COD)Rh(MeNO(2))(x)]CF3SO3 gave [(mu-C(5)H(5)BMe){Rh(COD)}2CF3SO3 (10). The structures of the two triple-decker complexes 4 and10 were determined by X-ray diffraction. Boratabenzene transfer reactions were found for the heterobimetallic salts 5-7.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 30/09/20 alle ore 11:31:40