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Titolo:
SELECTIVE AROMATIC CHLORINATION OF ACTIVATED ARENES WITH SODIUM-CHLORITE, (SALEN)MANGANESE(III) COMPLEX, AND ALUMINA IN DICHLOROMETHANE
Autore:
HIRANO M; YAKABE S; MONOBE H; MORIMOTO T;
Indirizzi:
TOKYO UNIV AGR & TECHNOL,FAC TECHNOL,DEPT APPL CHEM TOKYO 184 JAPAN
Titolo Testata:
Canadian journal of chemistry
fascicolo: 12, volume: 75, anno: 1997,
pagine: 1905 - 1912
SICI:
0008-4042(1997)75:12<1905:SACOAA>2.0.ZU;2-J
Fonte:
ISI
Lingua:
ENG
Soggetto:
REGIOSELECTIVE PARA CHLORINATION; SUPPORTED COPPER(II) HALIDES; SILICA-GEL; ACIDIC SOLUTION; N-CHLOROAMINES; CARBOXYLIC-ACIDS; ASYMMETRIC EPOXIDATION; HYDROGEN-PEROXIDE; SULFURYL CHLORIDE; RING-SYSTEM;
Keywords:
AROMATIC CHLORINATION; ALKYL ARYL ETHERS; SODIUM CHLORITE; (SALEN)MANGANESE(III) COMPLEX; ALUMINA;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
78
Recensione:
Indirizzi per estratti:
Citazione:
M. Hirano et al., "SELECTIVE AROMATIC CHLORINATION OF ACTIVATED ARENES WITH SODIUM-CHLORITE, (SALEN)MANGANESE(III) COMPLEX, AND ALUMINA IN DICHLOROMETHANE", Canadian journal of chemistry, 75(12), 1997, pp. 1905-1912

Abstract

The reaction of alkyl phenyl ethers with sodium chlorite in dichloromethane in the presence of a (salen)manganese(III) complex and alumina preloaded with a small amount of water afforded monochlorination products with unusually high para selectivities under mild conditions. The NaClO2-based biphasic system can also be successfully used for the regioselective monochlorination of substituted anisoles and polymethoxybenzenes.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 13/07/20 alle ore 09:37:13