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Titolo:
PHOSPHINOMETHANIDE VERSUS PHOSPHINOENOLATE - THERMODYNAMICAL PREFERENCE FOR A 3-MEMBERED INSTEAD OF A 5-MEMBERED CHELATE RING
Autore:
HENIG G; SCHULZ M; WERNER H;
Indirizzi:
UNIV WURZBURG,INST ANORGAN CHEM,HUBLAND D-97074 WURZBURG GERMANY UNIV WURZBURG,INST ANORGAN CHEM D-97074 WURZBURG GERMANY
Titolo Testata:
Chemical communications
fascicolo: 24, , anno: 1997,
pagine: 2349 - 2350
SICI:
1359-7345(1997):24<2349:PVP-TP>2.0.ZU;2-4
Fonte:
ISI
Lingua:
ENG
Soggetto:
METAL-CONTAINING HETEROCYCLES; ORGANOMETALLIC COMPLEXES; COORDINATION CHEMISTRY; CATALYST PRECURSORS; LIGANDS; NICKEL;
Tipo documento:
Article
Natura:
Periodico
Citazioni:
20
Recensione:
Indirizzi per estratti:
Citazione:
G. Henig et al., "PHOSPHINOMETHANIDE VERSUS PHOSPHINOENOLATE - THERMODYNAMICAL PREFERENCE FOR A 3-MEMBERED INSTEAD OF A 5-MEMBERED CHELATE RING", Chemical communications, (24), 1997, pp. 2349-2350

Abstract

The phosphinoenolate complex 4, which is prepared stepwise from [(mes)RuCl2](2) 1 via the neutral and cationic compounds 2 and 3 as isolated intermediates, rearranges slowly in benzene to the thermodynamicallymore stable phosphinomethanide isomer 5; the presence of a three-membered RuCP ring in the latter is confirmed by X-ray crystallography.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 01/12/20 alle ore 08:52:39