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Titolo:
Self-assembly, crystal structure, and magnetic properties of a phenoxo-bridged tetranuclear Cu-II complex of the [2x2] grid type
Autore:
Rojo, J; Lehn, JM; Baum, G; Fenske, D; Waldmann, O; Muller, P;
Indirizzi:
Univrg,rasbourg 1, ESA CNRS 7006, ISIS, Lab Chim Supramol, F-67000 Strasbou Univ Strasbourg 1 Strasbourg France F-67000 m Supramol, F-67000 Strasbou Univ Karlsruhe, Inst Anorgan Chem, D-76128 Karlsruhe, Germany Univ Karlsruhe Karlsruhe Germany D-76128 hem, D-76128 Karlsruhe, Germany Univ Erlangen Nurnberg, Inst Phys 3, D-91058 Erlangen, Germany Univ Erlangen Nurnberg Erlangen Germany D-91058 -91058 Erlangen, Germany
Titolo Testata:
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
fascicolo: 3, , anno: 1999,
pagine: 517 - 522
SICI:
1434-1948(199903):3<517:SCSAMP>2.0.ZU;2-S
Fonte:
ISI
Lingua:
ENG
Soggetto:
BINUCLEAR COPPER(II) COMPLEXES; COORDINATION ARRAYS; HEMOCYANIN MODELS; LIGAND; PERCHLORATE;
Keywords:
self-assembly; tetranuclear Cu-II complex; [2 x 2] grid-type complex; crystal structure; magnetic properties;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
28
Recensione:
Indirizzi per estratti:
Indirizzo: Lehn, JM Univrg,rasbourg 1, ESA CNRS 7006, ISIS, Lab Chim Supramol, F-67000 Strasbou Univ Strasbourg 1 Strasbourg France F-67000 l, F-67000 Strasbou
Citazione:
J. Rojo et al., "Self-assembly, crystal structure, and magnetic properties of a phenoxo-bridged tetranuclear Cu-II complex of the [2x2] grid type", EUR J INORG, (3), 1999, pp. 517-522

Abstract

The ditopic ligand 3 has been synthesized. In its deprotonated form, it reacts with copper(II) ions to form a tetranuclear complex 1 of the [2 x 2] Cu-4(II) grid type, the structure of which has been confirmed by X-ray crystallography. Magnetic studies of complex 1 indicate a very weak antiferromagnetic coupling between the phenoxo-bridged Cu-II ions.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 24/09/20 alle ore 04:58:21