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Titolo:
Use of 2-methyl-1-phenylpropan-2-yl hydroperoxide (MPPH) as a mechanistic probe for the heterolytic versus homolytic O-O bond cleavage of tert-alkyl hydroperoxide by iron(III) porphyrin complex
Autore:
Nam, W; Choi, HJ; Han, HJ; Cho, SH; Lee, HJ; Han, SY;
Indirizzi:
Ewha Womans Univ, Dept Chem, Seoul 120750, South Korea Ewha Womans Univ Seoul South Korea 120750 hem, Seoul 120750, South Korea Ewha Womans Univ, Ctr Cell Signaling Res, Seoul 120750, South Korea Ewha Womans Univ Seoul South Korea 120750 Res, Seoul 120750, South Korea
Titolo Testata:
CHEMICAL COMMUNICATIONS
fascicolo: 4, , anno: 1999,
pagine: 387 - 388
SICI:
1359-7345(19990221):4<387:UO2H(A>2.0.ZU;2-I
Fonte:
ISI
Lingua:
ENG
Soggetto:
AQUEOUS-SOLUTION; OXOIRON(IV) PORPHYRINS; CIS-STILBENE; EPOXIDATION; OXIDATION; ALKENES; FUNCTIONALIZATION; REACTIVITY; CATALYSTS; SCISSION;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
25
Recensione:
Indirizzi per estratti:
Indirizzo: Nam, W Ewha Womans Univ, Dept Chem, Seoul 120750, South Korea Ewha Womans Univ Seoul South Korea 120750 oul 120750, South Korea
Citazione:
W. Nam et al., "Use of 2-methyl-1-phenylpropan-2-yl hydroperoxide (MPPH) as a mechanistic probe for the heterolytic versus homolytic O-O bond cleavage of tert-alkyl hydroperoxide by iron(III) porphyrin complex", CHEM COMMUN, (4), 1999, pp. 387-388

Abstract

The mechanism of the O-O bond cleavage of tert-alkyl hydroperoxide by iron(III) porphyrin complexes has been studied using 2-methyl-1-phenylpropan-2-yl hydroperoxide (MPPH) as a mechanistic probe; the hydroperoxide O-O bond is cleaved both heterolytically and homolytically and partitioning between the two pathways significantly depends on the reaction conditions such as the pH of the reaction solutions and the nature of porphyrin and axial ligands.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 01/04/20 alle ore 11:10:28