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Titolo: ELECTROPHILIC METAL PRECURSORS AND A BETA-DIIMINE LIGAND FOR NICKEL(II)-CATALYZED AND PALLADIUM(II)-CATALYZED ETHYLENE POLYMERIZATIONS
Autore: FELDMAN J; MCLAIN SJ; PARTHASARATHY A; MARSHALL WJ; CALABRESE JC; ARTHUR SD;
- Indirizzi:
- DUPONT CO INC,CENT RES & DEV,EXPT STN WILMINGTON DE 19880
- Titolo Testata:
- Organometallics
fascicolo: 8,
volume: 16,
anno: 1997,
pagine: 1514 - 1516
- SICI:
- 0276-7333(1997)16:8<1514:EMPAAB>2.0.ZU;2-K
- Fonte:
- ISI
- Lingua:
- ENG
- Soggetto:
- NORBORNENE DERIVATIVES; TRANSITION; OLEFINS; COMPLEXES; CATALYSIS; CATIONS; IONS;
- Tipo documento:
- Article
- Natura:
- Periodico
- Settore Disciplinare:
- Science Citation Index Expanded
- Science Citation Index Expanded
- Citazioni:
- 25
- Recensione:
- Indirizzi per estratti:
-
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- Citazione:
- J. Feldman et al., "ELECTROPHILIC METAL PRECURSORS AND A BETA-DIIMINE LIGAND FOR NICKEL(II)-CATALYZED AND PALLADIUM(II)-CATALYZED ETHYLENE POLYMERIZATIONS", Organometallics, 16(8), 1997, pp. 1514-1516
Abstract
The alpha-diimine ligand ArN=C(Me)C(Me)=NAr (Ar = 2,6-C6H3-Pr-i(2)) reacts with Pd(OAc)(2) in the presence of HBF4 . Et2O, or [Pd(MeCN)(4)](BF4)(2) in the absence of acid, to give ethylene polymerization catalysts. The reactions of a related beta-diimine ligand with [Pd(MeCN)(4)]-(BF4)(2) and (1,2-dimethoxyethoxyethane)NiBr2, and the polymerization activity of catalysts derived from it, are discussed.
ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 26/11/20 alle ore 18:38:11