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Titolo:
Stereoselective synthesis of the pheromone (R)-(-)-sulcatol, and its enantiopure (R)- and (S)1-mono-, 1,1-di-, and -1,1,1-trifluoro analogues
Autore:
Arnone, A; Bravo, P; Panzeri, W; Viani, F; Zanda, M;
Indirizzi:
CNR, Ctr Studio Sostanze Org Nat, I-20131 Milan, Italy CNR Milan Italy I-20131 tr Studio Sostanze Org Nat, I-20131 Milan, Italy Dipartimento Chim Politecn, I-20131 Milan, Italy Dipartimento Chim Politecn Milan Italy I-20131 ecn, I-20131 Milan, Italy
Titolo Testata:
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
fascicolo: 1, , anno: 1999,
pagine: 117 - 127
SICI:
1434-193X(199901):1<117:SSOTP(>2.0.ZU;2-T
Fonte:
ISI
Lingua:
ENG
Soggetto:
CHIRAL BETA-KETOSULFOXIDES; ORGANIC SULFUR-COMPOUNDS; ASYMMETRIC-SYNTHESIS; ENANTIOSELECTIVE SYNTHESIS; GNATHOTRICHUS-SULCATUS; AGGREGATION PHEROMONE; ABSOLUTE-CONFIGURATION; SECONDARY ALCOHOLS; CARBOXYLIC-ACIDS; SCOLYTID BEETLE;
Keywords:
fluorine; pheromones; sulfoxides; sulcatol; asymmetric synthesis;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Physical, Chemical & Earth Sciences
Citazioni:
72
Recensione:
Indirizzi per estratti:
Indirizzo: Bravo, P CNR, Ctr Studio Sostanze Org Nat, Via Mancinelli 7, I-20131 Milan, Italy CNR Via Mancinelli 7 Milan Italy I-20131 7, I-20131 Milan, Italy
Citazione:
A. Arnone et al., "Stereoselective synthesis of the pheromone (R)-(-)-sulcatol, and its enantiopure (R)- and (S)1-mono-, 1,1-di-, and -1,1,1-trifluoro analogues", EUR J ORG C, (1), 1999, pp. 117-127

Abstract

The pheromone (R)-(-)-sulcatol (10a) and three of its enantiomeric mono-, di-, and trifluoro analogues 10b-d have been synthesized, in six steps and with good overall yields, starting from chiral (R)-2-methyl-5-[(4-methylphenyl)sulfinyl]pent-2-ene (1) and commercially available fluorinated or non-fluorinated acetates.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 10/07/20 alle ore 12:27:16