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Titolo:
THE PREPARATION AND X-RAY STRUCTURE OF [NBU4][FAC-PTBR3(S4N4)]
Autore:
GINN VC; KELLY PF; SLAWIN AMZ; WILLIAMS DJ; WOOLLINS JD;
Indirizzi:
UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM LONDON SW7 2AY ENGLAND UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM LONDON SW7 2AY ENGLAND
Titolo Testata:
Polyhedron
fascicolo: 10, volume: 12, anno: 1993,
pagine: 1135 - 1139
SICI:
0277-5387(1993)12:10<1135:TPAXSO>2.0.ZU;2-4
Fonte:
ISI
Lingua:
ENG
Soggetto:
SULFUR NITROGEN LIGANDS; COMPLEXES; S4N4;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Science Citation Index Expanded
Citazioni:
11
Recensione:
Indirizzi per estratti:
Citazione:
V.C. Ginn et al., "THE PREPARATION AND X-RAY STRUCTURE OF [NBU4][FAC-PTBR3(S4N4)]", Polyhedron, 12(10), 1993, pp. 1135-1139

Abstract

Reaction of [NBu4][Pt2Br6] with S4N4 gives the title compound, which has been characterized by N-15/Pt-195 NMR and X-ray crystallography. The anion consists of fused PtS2N2 and PtS3N2 rings with coordination to the platinum via two sulphur atoms and one nitrogen. The five-membered ring is essentially planar, whereas the six-membered ring is planarwith the exception of the coordinated sulphur atom which is common toboth rings. The N-S-N angles can be related to the magnitude of the 2J{N-15-N-15} coupling constants.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 04/12/20 alle ore 19:31:18