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Titolo:
THE REACTIVITY OF SE4N4 IN LIQUID-AMMONIA
Autore:
KELLY PF; WOOLLINS JD;
Indirizzi:
UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM LONDON SW7 2AY ENGLAND UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM LONDON SW7 2AY ENGLAND
Titolo Testata:
Polyhedron
fascicolo: 10, volume: 12, anno: 1993,
pagine: 1129 - 1133
SICI:
0277-5387(1993)12:10<1129:TROSIL>2.0.ZU;2-H
Fonte:
ISI
Lingua:
ENG
Soggetto:
X-RAY STRUCTURE; COMPLEXES; CATIONS;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Science Citation Index Expanded
Citazioni:
12
Recensione:
Indirizzi per estratti:
Citazione:
P.F. Kelly e J.D. Woollins, "THE REACTIVITY OF SE4N4 IN LIQUID-AMMONIA", Polyhedron, 12(10), 1993, pp. 1129-1133

Abstract

Tetraselenium-tetranitride, Se4N4, dissolves in liquid ammonia at high pressure (ca 50 atm.) and reacts with PtCl2(PMe2Ph)2 to give Pt(Se2N2)(PMe2Ph)2 in quantitative yield. If the reaction is performed using (Se4N4)-N-15 the product is obtained with a low ( < 20%) degree of N-15 labelling; in contrast (Se4N4)-N-15 may be recrystallized from ammonia with no loss of N-15 content, indicating that, unlike S4N4, it doesnot react with ammonia as it dissolves.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 02/12/20 alle ore 05:07:19