Catalogo Articoli (Spogli Riviste)

OPAC HELP

Titolo:
SYNTHESES, ELECTROCHEMISTRY AND MOLECULAR MODELING OF N,N'-DICYANOQUINONEDIIMINE (DCNQI) DERIVATIVES OF SUBSTITUTED 1,4-ANTHRACENEDIONES - PRECURSORS FOR ORGANIC METALS
Autore:
BARRANCO E; MARTIN N; SEGURA JL; SEOANE C; DELACRUZ P; LANGA F; GONZALEZ A; PINGARRON JM;
Indirizzi:
UNIV COMPLUTENSE MADRID,FAC QUIM,DEPT QUIM ORGAN E-28040 MADRID SPAIN UNIV COMPLUTENSE MADRID,FAC QUIM,DEPT QUIM ORGAN E-28040 MADRID SPAIN UNIV CASTILLA LA MANCHA,FAC QUIM,DEPT QUIM ORGAN INORGAN & BIOQUIM E-45001 TOLEDO SPAIN UNIV COMPLUTENSE MADRID,FAC QUIM,DEPT QUIM ANALIT E-28040 MADRID SPAIN
Titolo Testata:
Tetrahedron
fascicolo: 22, volume: 49, anno: 1993,
pagine: 4881 - 4892
SICI:
0040-4020(1993)49:22<4881:SEAMMO>2.0.ZU;2-E
Fonte:
ISI
Lingua:
ENG
Soggetto:
REVERSIBLE REDOX SYSTEMS; ELECTRON-ACCEPTORS; ANION; SALTS;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
22
Recensione:
Indirizzi per estratti:
Citazione:
E. Barranco et al., "SYNTHESES, ELECTROCHEMISTRY AND MOLECULAR MODELING OF N,N'-DICYANOQUINONEDIIMINE (DCNQI) DERIVATIVES OF SUBSTITUTED 1,4-ANTHRACENEDIONES - PRECURSORS FOR ORGANIC METALS", Tetrahedron, 49(22), 1993, pp. 4881-4892

Abstract

The title compounds (10) have been obtained from the corresponding 1,4-anthracenedione derivatives (3), prepared by different synthetic routes, by reaction with bis(trimethylsilyl)carbodiimide (BTC). The cyclic voltammetry of these compounds (3 and 10) reveals the presence of two reduction waves to the corresponding anion-radical and dianion. The acceptor ability of compounds 10 can be modulated by the presence of substituents on the DCNQI ring. The syn/anti isomers have been studied by molecular mechanics and the results are in good agreement with the H-1-NMR high resolution spectral data.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 04/12/20 alle ore 16:23:41