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Titolo:
SOLVENT EFFECTS ON MOLECULAR AND IONIC SPECTRA-IX - THE CHANGE IN DIPOLE-MOMENT ACCOMPANYING METAL TO LIGAND CHARGE-TRANSFER ABSORPTION IN PENTAAMINOPYRIDYLRUTHENIUM(II)
Autore:
ZENG J; HUSH NS; REIMERS JR;
Indirizzi:
UNIV SYDNEY,SCH CHEM F11 SYDNEY NSW 2006 AUSTRALIA UNIV SYDNEY,SCH CHEM F11 SYDNEY NSW 2006 AUSTRALIA UNIV SYDNEY,DEPT BIOCHEM SYDNEY NSW 2006 AUSTRALIA
Titolo Testata:
Journal of physical chemistry
fascicolo: 50, volume: 100, anno: 1996,
pagine: 19292 - 19294
SICI:
0022-3654(1996)100:50<19292:SEOMAI>2.0.ZU;2-Z
Fonte:
ISI
Lingua:
ENG
Soggetto:
INTERMEDIATE NEGLECT; STARK SPECTROSCOPY; DILUTE PYRIMIDINE; MIXED-VALENCE; NUCLEIC-ACIDS; FORCE-FIELD; FREE-ENERGY; WATER; COMPLEXES; STATE;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
30
Recensione:
Indirizzi per estratti:
Citazione:
J. Zeng et al., "SOLVENT EFFECTS ON MOLECULAR AND IONIC SPECTRA-IX - THE CHANGE IN DIPOLE-MOMENT ACCOMPANYING METAL TO LIGAND CHARGE-TRANSFER ABSORPTION IN PENTAAMINOPYRIDYLRUTHENIUM(II)", Journal of physical chemistry, 100(50), 1996, pp. 19292-19294

Abstract

We have previously modeled solvent effects on the metal to ligand charge transfer (MLCT) spectra of Ru2+-(NH3)(5)-pyrazine, Ru2+(NH3)(5)-pyrazine-H+, and Ru2+(NH3)(5)-pyridine and predicted the change Delta muin dipole moment on excitation of Ru2+(NH3)(5)-pyrazine and Ru2+(NH3)(5)-pyrazine-H+. Prompted by a recent observation of Delta mu for Ru2+(NH3)(5)-pyridine by electroabsorption spectroscopy, we review the results of our previous simulations and evaluate Delta mu. The agreement found between the observed and a priori calculated values is not as close as found for the other complexes but, given the difficulties involved in both the theory and experiment, is very encouraging.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 24/11/20 alle ore 21:41:18