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Titolo:
THE CRYSTAL AND MOLECULAR-STRUCTURE OF BIS(INDAZOL-1-YL)PYRIDIN-2'-YLMETHANE (BIPM) AND [RH(BIPM)(NBD)]PF6
Autore:
GALLEGOPRECIADO MCL; BALLESTEROS P; CLARAMUNT RM; CANO M; HERAS JV; PINILLA E; MONGE A;
Indirizzi:
UNED,FAC CIENCIAS,DEPT QUIM ORGAN & BIOL E-28040 MADRID SPAIN UNIV COMPLUTENSE MADRID,FAC CIENCIAS QUIM,DEPT QUIM INORGAN 1 E-28040MADRID SPAIN CSIC,INST CIENCIAS MAT SEDE D E-28040 MADRID SPAIN UNIV COMPLUTENSE MADRID,FAC QUIM,DIFRACC RAYOS X LAB E-28040 MADRID SPAIN UNIV CASTILLA LA MANCHA,EU POLITECN ALMADEN,DEPT QUIM INORGAN ORGAN &BIOQUIM ALMADEN SPAIN
Titolo Testata:
Journal of organometallic chemistry
fascicolo: 1-2, volume: 450, anno: 1993,
pagine: 237 - 244
SICI:
0022-328X(1993)450:1-2<237:TCAMOB>2.0.ZU;2-#
Fonte:
ISI
Lingua:
ENG
Soggetto:
NITROGEN-DONOR LIGANDS; RUTHENIUM(II) COMPLEXES; COORDINATION CHEMISTRY; TRIDENTATE LIGANDS; SPECTROSCOPY; ELECTROCHEMISTRY; DERIVATIVES; SERIES;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Science Citation Index Expanded
Citazioni:
30
Recensione:
Indirizzi per estratti:
Citazione:
M.C.L. Gallegopreciado et al., "THE CRYSTAL AND MOLECULAR-STRUCTURE OF BIS(INDAZOL-1-YL)PYRIDIN-2'-YLMETHANE (BIPM) AND [RH(BIPM)(NBD)]PF6", Journal of organometallic chemistry, 450(1-2), 1993, pp. 237-244

Abstract

The syntheses of a new tripodal ligand bis(indazol-1-yl)pyridin-2'-ylmethane (BIPM) and of a cationic complex [Rh(BIPM)(NBD)]PF6, (NBD = 2,5-norbornadiene) are reported. Both compounds were characterized by infrared, H-1, and C-13 NMR spectroscopy and by single crystal X-ray analysis. BIPM crystallizes in the monoclinic system in space group P2(1)/n with an alphabetaalpha helical conformation. The [Rh(BIPM)(NBD)]PF6complex crystallizes in the monoclinic space group C/2c, the rhodium atom being pentacoordinate with a distorted trigonal bipyramidal geometry.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 02/07/20 alle ore 22:36:42