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Titolo:
SYNTHESIS AND ELECTROCHEMICAL PROPERTIES OF DINUCLEAR MANGANESE(II) COMPLEXES WITH OCTADENTATE SCHIFF-BASE MACROCYCLES - FINE-TUNING OF THEREDOX BEHAVIOR
Autore:
IKAWA Y; NAGATA T; MARUYAMA K;
Indirizzi:
KYOTO UNIV,FAC SCI,DEPT CHEM KYOTO 606 JAPAN KYOTO UNIV,FAC SCI,DEPT CHEM KYOTO 606 JAPAN
Titolo Testata:
Chemistry Letters
fascicolo: 6, , anno: 1993,
pagine: 1049 - 1052
SICI:
0366-7022(1993):6<1049:SAEPOD>2.0.ZU;2-N
Fonte:
ISI
Lingua:
ENG
Soggetto:
BINUCLEAR MANGANESE(II); PHOTOSYSTEM-II; 1,5-BIS(SALICYLIDENEAMINO)-3-PENTANOL; TETRANUCLEAR; OXIDATION; SITES;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
27
Recensione:
Indirizzi per estratti:
Citazione:
Y. Ikawa et al., "SYNTHESIS AND ELECTROCHEMICAL PROPERTIES OF DINUCLEAR MANGANESE(II) COMPLEXES WITH OCTADENTATE SCHIFF-BASE MACROCYCLES - FINE-TUNING OF THEREDOX BEHAVIOR", Chemistry Letters, (6), 1993, pp. 1049-1052

Abstract

A series of dinuclear manganese(II) complexes [R1-LMn2(R2CO2)]ClO4 were synthesized and X-ray crystal structure analysis of [CH3-LMn2(CH3CO2)]ClO4 (1) was performed. Two manganese ions of 1 were six-coordinatewith highly deformed octahedral structure. Electrochemical measurements of these complexes revealed that both the substituents of the phenol ring and those on the ligating acetate effectively control the redoxproperties of the Mn(II) center.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 29/03/20 alle ore 09:15:04