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Titolo:
BENZOYLMETHYLENETRIPHENYLPHOSPHORANE, C26H21OP
Autore:
KALYANASUNDARI M; PANCHANATHESWARAN K; PARTHASARATHI V; ROBINSON WT; WEN H;
Indirizzi:
BHARATHIDASAN UNIV,DEPT CHEM TIRUCHCHIRAPPALLI 620024 INDIA BHARATHIDASAN UNIV,DEPT PHYS TIRUCHCHIRAPPALLI 620024 INDIA UNIV CANTERBURY,DEPT CHEM CHRISTCHURCH 1 NEW ZEALAND
Titolo Testata:
Acta crystallographica. Section C, Crystal structure communications
, volume: 50, anno: 1994,
parte:, 11
pagine: 1738 - 1741
SICI:
0108-2701(1994)50:<1738:BC>2.0.ZU;2-W
Fonte:
ISI
Lingua:
ENG
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
10
Recensione:
Indirizzi per estratti:
Citazione:
M. Kalyanasundari et al., "BENZOYLMETHYLENETRIPHENYLPHOSPHORANE, C26H21OP", Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 1738-1741

Abstract

The air-stable phosphorane (2-oxo-2-phenyltriphenylphosphoniumethylide) is shown to be a resonance hybrid of an ylene, ylidic and enolate canonical assembly. The geometry around the P atom is nearly tetrahedral. The O atom is oriented cis to the P atom. The phenyl ring of the benzoyl group is twisted with respect to the plane containing the carbonyl group.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 25/10/20 alle ore 12:24:29