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Titolo:
OXIDATION REACTIONS WITH HOF AND ADDUCTS OF HOF AND HF WITH ACETONITRILE
Autore:
DUNKELBERG O; HAAS A; KLAPDOR MF; MOOTZ D; POLL W; APPELMAN EH;
Indirizzi:
RUHRUNIV BOCHUM,LEHRSTUHL ANORGAN CHEM 2 D-44780 BOCHUM GERMANY RUHRUNIV BOCHUM,LEHRSTUHL ANORGAN CHEM 2 D-44780 BOCHUM GERMANY UNIV DUSSELDORF,INST ANORGAN CHEM & STRUKTURCHEM D-40225 DUSSELDORF GERMANY ARGONNE NATL LAB,DIV CHEM ARGONNE IL 60439
Titolo Testata:
Chemische Berichte
fascicolo: 10, volume: 127, anno: 1994,
pagine: 1871 - 1875
SICI:
0009-2940(1994)127:10<1871:ORWHAA>2.0.ZU;2-0
Fonte:
ISI
Lingua:
GER
Soggetto:
HYPOFLUOROUS ACID; FLUORIDES;
Keywords:
OXIDATION BY HOF; HYPOFLUOROUS ACID; ADDITION COMPOUNDS OF HOF AND HF WITH ACETONITRILE;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
17
Recensione:
Indirizzi per estratti:
Citazione:
O. Dunkelberg et al., "OXIDATION REACTIONS WITH HOF AND ADDUCTS OF HOF AND HF WITH ACETONITRILE", Chemische Berichte, 127(10), 1994, pp. 1871-1875

Abstract

In acetonitrile solution HOF oxides CF3SSCF3 via CF3S(O)(n)SCF3 (n = 1, 2) to yield [CF3S(O)2]2O. Analogously, CF3Se(O)OH and CF3SeX (X = Cl, Br) are oxidized via CF3Se(VI) intermediates to provide finally [CF3Se(O)2]2O. With CH3CN at low temperatures HOF and HF form 1:1 adducts, whose structures have been elucidated by low-temperature X-ray structure analysis. Additional proof for the formation of CH3CN . HF in theliquid phase is provided.

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Documento generato il 24/10/20 alle ore 19:38:26