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Titolo:
4,7-DIAZADECANEDIAMIDE)-DIISOTHIOCYANATOCOPPER(II)
Autore:
LIN JL; LU TH; TAHIROV TH; LIU YL; CHI TY; CHUNG CS;
Indirizzi:
NATL TSING HUA UNIV,DEPT PHYS HSINCHU 300 TAIWAN NATL TSING HUA UNIV,DEPT CHEM HSINCHU 300 TAIWAN
Titolo Testata:
Acta crystallographica. Section C, Crystal structure communications
, volume: 50, anno: 1994,
parte:, 7
pagine: 1003 - 1005
SICI:
0108-2701(1994)50:<1003:4>2.0.ZU;2-W
Fonte:
ISI
Lingua:
ENG
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
6
Recensione:
Indirizzi per estratti:
Citazione:
J.L. Lin et al., "4,7-DIAZADECANEDIAMIDE)-DIISOTHIOCYANATOCOPPER(II)", Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 1003-1005

Abstract

The Cu(II) ion of the title complex, [Cu(NCS)2(C10H22O2N4)], is six-coordinated in a tetragonally elongated octahedral geometry with the two amine N atoms of the quadridentate ligand and the two N atoms of theisothiocyanato groups equatorial and the two amide O atoms axial. Thetwo N-methyl groups of the tetradentate ligand are trans to each other with respect to the equatorial plane. The complex has a cis-alpha conformation. The central five-membered ring is in a stable skew form and both of the terminal six-membered rings are in unstable twist forms. Both isothiocyanato groups are disordered.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 14/07/20 alle ore 19:49:30