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Titolo:
INSERTION OF ACETYLENE INTO THE RU-SI BOND OF A BIS(MU-SILYLENE) COMPLEX - SYNTHESIS AND STRUCTURE OF A 2,5-DISILARUTHENACYCLOPENTENE COMPLEX
Autore:
TAKAO T; SUZUKI H; TANAKA M;
Indirizzi:
TOKYO INST TECHNOL,FAC ENGN,DEPT CHEM ENGN,MEGURO KU TOKYO 152 JAPAN TOKYO INST TECHNOL,FAC ENGN,DEPT CHEM ENGN,MEGURO KU TOKYO 152 JAPAN TOKYO INST TECHNOL,RESOURCES UTILIZAT RES LAB,MIDORI KU YOKOHAMA KANAGAWA 227 JAPAN
Titolo Testata:
Organometallics
fascicolo: 7, volume: 13, anno: 1994,
pagine: 2554 - 2556
SICI:
0276-7333(1994)13:7<2554:IOAITR>2.0.ZU;2-8
Fonte:
ISI
Lingua:
ENG
Soggetto:
SILYL HYDRIDE COMPLEXES; METAL SILICON BONDS; O-DONOR LIGAND; ETA-2-SILANIMINE COMPLEXES; CATALYZED HYDROSILATION; ALKYNE HYDROSILYLATION; PRIMARY ORGANOSILANES; METATHESIS MECHANISM; SILANES; POLYSILANES;
Tipo documento:
Note
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Science Citation Index Expanded
Citazioni:
46
Recensione:
Indirizzi per estratti:
Citazione:
T. Takao et al., "INSERTION OF ACETYLENE INTO THE RU-SI BOND OF A BIS(MU-SILYLENE) COMPLEX - SYNTHESIS AND STRUCTURE OF A 2,5-DISILARUTHENACYCLOPENTENE COMPLEX", Organometallics, 13(7), 1994, pp. 2554-2556

Abstract

Treatment of the bis(A-silylene) complex [Cp'Ru(mu-SiPh2)(mu-H)]2 (3)with acetylene yields the mu-2,5-1-disilaruthenacyclopentene complex Cp'Ru(mu-SiPh2CH=CHSiPh2)(mu-H)2RuCp'(4) as a result of the insertion of C2H2 into a Ru-Si bond of 3. The reaction of 4 with H-2 results in cleavage of a Si-C bond of the metallacycle to form the mu-vinylsilyl complex Cp'2-Ru2(SiPh2CH=CH2)(mu-eta2-HSiPh2)(mu-H)(H) (5). The molecular structure of 4 was determined by single-crystal X-ray diffraction.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 27/11/20 alle ore 01:59:12