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Titolo:
A SOLUBLE POLYMER-BOUND APPROACH TO THE SHARPLESS CATALYTIC ASYMMETRIC DIHYDROXYLATION (AD) REACTION - PREPARATION AND APPLICATION OF A [(DHQD)(2)PHAL-PEG-OME] LIGAND
Autore:
HAN HS; JANDA KD;
Indirizzi:
SCRIPPS CLIN & RES INST,DEPT CHEM,10666 N TORREY PINES RD LA JOLLA CA92037 SCRIPPS CLIN & RES INST,DEPT CHEM LA JOLLA CA 92037 SKAGGS INST CHEM BIOL LA JOLLA CA 92037
Titolo Testata:
Tetrahedron letters
fascicolo: 9, volume: 38, anno: 1997,
pagine: 1527 - 1530
SICI:
0040-4039(1997)38:9<1527:ASPATT>2.0.ZU;2-1
Fonte:
ISI
Lingua:
ENG
Soggetto:
PROCESS IMPROVEMENT; OLEFINS; ALKENES; SUPPORT;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
22
Recensione:
Indirizzi per estratti:
Citazione:
H.S. Han e K.D. Janda, "A SOLUBLE POLYMER-BOUND APPROACH TO THE SHARPLESS CATALYTIC ASYMMETRIC DIHYDROXYLATION (AD) REACTION - PREPARATION AND APPLICATION OF A [(DHQD)(2)PHAL-PEG-OME] LIGAND", Tetrahedron letters, 38(9), 1997, pp. 1527-1530

Abstract

The synthesis of a soluble polymer-bound (DHQD)(2)PHAL ligand 1 and its successful application in the catalytic asymmetric dihydroxylation reaction are described. The results highlight that the soluble polymer-bound ligand approach offers all the benefits associated with insoluble supports but with the key advantages of increased reactivity and enantioselectivity inherent with solution-phase methodology. (C) 1997 Elsevier Science Ltd.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 04/07/20 alle ore 14:52:59