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Titolo:
A BINUCLEAR COPPER(II) COMPLEX OF THE DEPROTONATED ANION OF N,N'-DIGLYCYLETHYLENEDIAMINE
Autore:
TAHIROV TH; LU TH; SHU K; CHUNG CS;
Indirizzi:
NATL TSING HUA UNIV,DEPT PHYS HSINCHU 300 TAIWAN NATL TSING HUA UNIV,DEPT CHEM HSINCHU 300 TAIWAN
Titolo Testata:
Acta crystallographica. Section C, Crystal structure communications
, volume: 50, anno: 1994,
parte:, 5
pagine: 708 - 710
SICI:
0108-2701(1994)50:<708:ABCCOT>2.0.ZU;2-O
Fonte:
ISI
Lingua:
ENG
Soggetto:
AMINO-ACIDS; NICKEL(II); LIGANDS; CRYSTAL;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
13
Recensione:
Indirizzi per estratti:
Citazione:
T.H. Tahirov et al., "A BINUCLEAR COPPER(II) COMPLEX OF THE DEPROTONATED ANION OF N,N'-DIGLYCYLETHYLENEDIAMINE", Acta crystallographica. Section C, Crystal structure communications, 50, 1994, pp. 708-710

Abstract

The title compound, kappaO';1kappaN'-kappaO':2kappa2N,N''-dicopper(II) diperchlorate tetrahydrate, [Cu2(C6H13N4O2)2(H2O)2]2ClO4.4H2O, in which only one of the two amide protons of each N,N'-diglycylethylenediamine is released in solution, exists as a binuclear complex with inversion symmetry in the solid state. Each Cu(II) ion is five-coordinate with a distorted square-pyramidal geometry. Two donar N atoms of one tetradentate ligand and one N atom and one O atom of the other ligand form a slightly distorted plane and a water O atom occupies the axial position. Hydrogen bonds help stabilize the crystal structure.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 15/07/20 alle ore 20:22:33