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Titolo:
PHOTOCHEMISTRY OF ACETONE IN THE PRESENCE OF EXOCYCLIC OLEFINS - AN UNEXPECTED COMPETITION BETWEEN THE PHOTO-CONIA AND PATERNO-BUCHI REACTIONS
Autore:
CHUNG WS; HO CC;
Indirizzi:
NATL CHIAO TUNG UNIV,DEPT APPL CHEM HSINCHU 30050 TAIWAN
Titolo Testata:
Chemical communications
fascicolo: 3, , anno: 1997,
pagine: 317 - 318
SICI:
1359-7345(1997):3<317:POAITP>2.0.ZU;2-D
Fonte:
ISI
Lingua:
ENG
Soggetto:
FACE SELECTIVITY; ENE REACTIONS; PHOTOCYCLOADDITION; ADAMANTAN-2-ONES;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
32
Recensione:
Indirizzi per estratti:
Citazione:
W.S. Chung e C.C. Ho, "PHOTOCHEMISTRY OF ACETONE IN THE PRESENCE OF EXOCYCLIC OLEFINS - AN UNEXPECTED COMPETITION BETWEEN THE PHOTO-CONIA AND PATERNO-BUCHI REACTIONS", Chemical communications, (3), 1997, pp. 317-318

Abstract

When irradiated in the presence of several exocyclic olefins, acetoneundergoes homoalkylation with the olefins to form a series of 4-cycloalkylbutan-2-ones (with quantum yields of 0.14 +/- 0.01) rather than exhibiting the expected Paterno-Buchi reaction; in contrast, the photolysis of perdeuteriated acetone gave both types of products.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 13/07/20 alle ore 07:13:41