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Titolo:
ENANTIOSELECTIVE SYNTHESIS OF 1,3-DIOXYGEN-SUBSTITUTED CHIRAL BUILDING-BLOCKS
Autore:
SENANAYAKE CH; LARSEN RD; BILL TJ; CORLEY EG; REIDER PJ;
Indirizzi:
MERCK & CO INC,RES LABS,DEPT PROC RES,POB 2000 RAHWAY NJ 07065
Titolo Testata:
Synlett
fascicolo: 3, , anno: 1994,
pagine: 199 - 200
SICI:
0936-5214(1994):3<199:ESO1CB>2.0.ZU;2-U
Fonte:
ISI
Lingua:
ENG
Soggetto:
ANGIOTENSIN-CONVERTING ENZYME; MICROBIAL CHEMISTRY; STREPTOMYCIN BIOSYNTHESIS; ASYMMETRIC-SYNTHESIS; A-FACTOR; ACID; ESTERS; INHIBITORS; INDUCER; DESIGN;
Tipo documento:
Note
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
27
Recensione:
Indirizzi per estratti:
Citazione:
C.H. Senanayake et al., "ENANTIOSELECTIVE SYNTHESIS OF 1,3-DIOXYGEN-SUBSTITUTED CHIRAL BUILDING-BLOCKS", Synlett, (3), 1994, pp. 199-200

Abstract

The extremely useful chiral building blocks 3-hydroxy-2-alkylpropionates 8 are prepared in either S or R enantiomeric form via the diastereoselective addition of chiral alcohols to arylketenes 4 and the manipulation of the resultant chiral 2-arylaliphatic esters 5 and 6. Application of this methodology to the asymmetric syntheses of 3-mercapto-2-alkylpropionates (9) and (S)-(-)-paraconic acid (3) is described.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 30/11/20 alle ore 10:14:07