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Titolo:
POLYSULFONYL AMINES .46. MOLECULAR ADDUCT S OF DI(ORGANOSULFONYL)AMINES WITH DIMETHYL-SULFOXIDE AND TRIPHENYLPHOSPHINE OXIDE - X-RAY STRUCTURE DETERMINATION OF DI(4-FLUOROBENZENESULFONYL)AMINE-DIMETHYL SULFOXIDE (2 1)/
Autore:
BLASCHETTE A; HAMANN T; HENSCHEL D; JONES PG;
Indirizzi:
TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST ANORGAN & ANALYT CHEM,POSTFACH 3329 D-38023 BRAUNSCHWEIG GERMANY
Titolo Testata:
Zeitschrift fur anorganische und allgemeine Chemie
fascicolo: 11, volume: 619, anno: 1993,
pagine: 1945 - 1950
SICI:
0044-2313(1993)619:11<1945:PA.MAS>2.0.ZU;2-H
Fonte:
ISI
Lingua:
GER
Soggetto:
CRYSTAL-STRUCTURE;
Keywords:
DI(ORGANOSULFONYL)AMINES; ADDITION COMPOUNDS WITH DIMETHYL SULFOXIDE; ADDITION COMPOUNDS WITH TRIPHENYLPHOSPHINE OXIDE; PREPARATION; CRYSTAL AND MOLECULAR STRUCTURE;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
15
Recensione:
Indirizzi per estratti:
Citazione:
A. Blaschette et al., "POLYSULFONYL AMINES .46. MOLECULAR ADDUCT S OF DI(ORGANOSULFONYL)AMINES WITH DIMETHYL-SULFOXIDE AND TRIPHENYLPHOSPHINE OXIDE - X-RAY STRUCTURE DETERMINATION OF DI(4-FLUOROBENZENESULFONYL)AMINE-DIMETHYL SULFOXIDE (2 1)/", Zeitschrift fur anorganische und allgemeine Chemie, 619(11), 1993, pp. 1945-1950

Abstract

From equimolar solutions of the respective components in CH2Cl2/petroleum ether, the following crystalline addition compounds were obtained: (X-C6H4SO2)2NH . OS(CH3)2, where X = H, 4-CH3, 4-Cl, 4-Br, 4-1, 4-NO2 Or 3-NO,; [(4-F-C6H4SO2)2NH]2 . OS(CH)3)2 (8); (4-1-C6H4SO2)2NH . OP(C6H5)3. A (2/1) complex of (4-F-C6H4SO2)2NH with OP(CH5)3 could not be isolated. The solid-state structure of the (2/1) compound 8 is compared with the known structure of the (1/1) complex (CH3SO2)2NH - OS(CH3)2. The crystallographic data for 8 at -95-degrees-C are: monoclinic, space group C2/c, a = 2369.9(13), b = 1006.8(4), c = 2 772.6(13) pm, beta = 11 0.71(4)-degrees, U = 6.187 nM3, Z = 8. Two N-H ... 0 hydrogenbonds with N ... 0 275 and 280 pm connect the disulfonylamine molecules with the dimethyl sulfoxide molecule. The 0 atom of the latter has a trigonal-planar environment consisting of the S atom and the two hydrogen bond H atoms.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 22/10/20 alle ore 09:26:50