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Titolo:
ETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE]NICKEL(II) DIPERCHLORATE
Autore:
TAHIROV TH; LU TH;
Indirizzi:
NATL TSING HUA UNIV,DEPT PHYS HSINCHU 300 TAIWAN NATL TSING HUA UNIV,DEPT PHYS HSINCHU 300 TAIWAN NATL TSING HUA UNIV,DEPT CHEM HSINCHU 300 TAIWAN
Titolo Testata:
Acta crystallographica. Section C, Crystal structure communications
, volume: 51, anno: 1995,
parte:, 10
pagine: 2018 - 2020
SICI:
0108-2701(1995)51:<2018:ED>2.0.ZU;2-W
Fonte:
ISI
Lingua:
ENG
Soggetto:
COMPLEXES; NICKEL(II); LIGANDS;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
7
Recensione:
Indirizzi per estratti:
Citazione:
T.H. Tahirov e T.H. Lu, "ETHYL-1,4,8,11-TETRAAZACYCLOTETRADECANE]NICKEL(II) DIPERCHLORATE", Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 2018-2020

Abstract

Two pseudosymmetrically related Ni-II complexes are located in the asymmetric unit of solid [Ni(C14H32N4)](ClO4)(2) The Ni2+ ion displays square-planar coordination with the four N atoms of the macrocyclic Ligand. The quadridentate ligand adopts its stable conformation with two six-membered chelate rings in chair forms and two five-membered chelate rings in skew forms. The complex has a 1RS,4RS,8SR,11SR configuration for the four chiral N-atom centres and a 5SR,7RS,12RS,14RS configuration for the four chiral C-atom centres.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 03/07/20 alle ore 01:40:32