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Titolo:
NOVEL CLUSTER-DERIVED CATALYSTS FOR THE SELECTIVE HYDROGENATION OF CROTONALDEHYDE
Autore:
BANARES M; PATIL AN; FEHLNER TP; WOLF EE;
Indirizzi:
UNIV NOTRE DAME,DEPT CHEM ENGN NOTRE DAME IN 46556 UNIV NOTRE DAME,DEPT CHEM ENGN NOTRE DAME IN 46556 UNIV NOTRE DAME,DEPT CHEM & BIOCHEM NOTRE DAME IN 46556
Titolo Testata:
Catalysis letters
fascicolo: 3-4, volume: 34, anno: 1995,
pagine: 251 - 258
SICI:
1011-372X(1995)34:3-4<251:NCCFTS>2.0.ZU;2-M
Fonte:
ISI
Lingua:
ENG
Soggetto:
1,3-BUTADIENE;
Keywords:
ORGANOMETALLIC CLUSTERS; CROTONALDEHYDE HYDROGENATION; SELECTIVE HYDROGENATION; NOVEL CATALYSTS FOR;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
19
Recensione:
Indirizzi per estratti:
Citazione:
M. Banares et al., "NOVEL CLUSTER-DERIVED CATALYSTS FOR THE SELECTIVE HYDROGENATION OF CROTONALDEHYDE", Catalysis letters, 34(3-4), 1995, pp. 251-258

Abstract

The controlled pyrolysis of transition metal cluster substituted metal carboxylates, e.g., M(4)O[(CO)(9)Co3CCO2](6), where M = Co and Zn, and M'(2){(CO)(9)Co3CCOO}(4), where M' = Co, Mo, and Cu, results in theformation of high surface area, amorphous solids that are active and selective catalysts for the hydrogenation of crotonaldehyde. In contrast to conventional metal catalysts that are selective for the double bond hydrogenation, these new solids exhibit high regioselectivities for the conversion of crotonaldehyde (2-butenal) to crotyl alcohol (2-butenol). Further, the observed selectivities depend on the metal cluster carboxylate structure.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 07/07/20 alle ore 15:05:40