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Titolo:
SELECTIVE MANIPULATION OF ONLY ONE OF 2 SIMILAR SITES WITHIN A MOLECULE ODIN-REACTIONS - STRATEGIC ADVANTAGE FOR SYNTHESIS AND TACTICS AVAILABLE
Autore:
MILNER DJ;
Indirizzi:
ZENECA SPECIALTIES RES CTR,HEXAGON HOUSE MANCHESTER M9 8ZS LANCS ENGLAND
Titolo Testata:
Journal of chemical technology and biotechnology
fascicolo: 4, volume: 63, anno: 1995,
pagine: 301 - 312
SICI:
0268-2575(1995)63:4<301:SMOOOO>2.0.ZU;2-W
Fonte:
ISI
Lingua:
ENG
Soggetto:
DERIVATIVES; CHEMISTRY; OXIDATION; DIOLS; MONOMETHYLATION; BROMINATION; PRODUCTS; AMINES; SYSTEM; NITRO;
Keywords:
ODIN; MONO; PARTIAL; SYNTHESIS; SELECTION; SYMMETRICAL;
Tipo documento:
Review
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Science Citation Index Expanded
Science Citation Index Expanded
Citazioni:
90
Recensione:
Indirizzi per estratti:
Citazione:
D.J. Milner, "SELECTIVE MANIPULATION OF ONLY ONE OF 2 SIMILAR SITES WITHIN A MOLECULE ODIN-REACTIONS - STRATEGIC ADVANTAGE FOR SYNTHESIS AND TACTICS AVAILABLE", Journal of chemical technology and biotechnology, 63(4), 1995, pp. 301-312

Abstract

Approaches used to effect selective reaction at one of two or more similar sites in a molecule are reviewed. The nature of the problem is defined and the strategic advantage to be gained through the use of symmetrical intermediates is outlined early and re-emphasised throughout the discussion with specific examples of multistage syntheses of important products. The various tactics used to effect site selectivity in a late synthetic step are described in a logical sequence and presented in a form aimed to help in the design of syntheses of unsymmetric products from symmetric intermediates.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 22/09/20 alle ore 18:32:34