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Titolo:
NOVEL ZIRCONIUM BOROHYDRIDE COMPLEXES - SYNTHESES AND MOLECULAR-STRUCTURES OF [ZR(ETA-C8H6(SIME(3))(2))(ETA(3)-BH4)(ETA(2)-BH4)] AND TA(6)ETA(4)-C8H6(SIME(3))(2))(MU-H)ZR(ETA(3)-BH4)]
Autore:
JOSEPH SCP; CLOKE FGN; CARDIN CJ; HITCHCOCK PB;
Indirizzi:
UNIV SUSSEX,SCH CHEM & MOLEC SCI BRIGHTON BN1 9QJ E SUSSEX ENGLAND UNIV SUSSEX,SCH CHEM & MOLEC SCI BRIGHTON BN1 9QJ E SUSSEX ENGLAND UNIV READING,DEPT CHEM READING RG6 2AD BERKS ENGLAND
Titolo Testata:
Organometallics
fascicolo: 7, volume: 14, anno: 1995,
pagine: 3566 - 3569
SICI:
0276-7333(1995)14:7<3566:NZBC-S>2.0.ZU;2-2
Fonte:
ISI
Lingua:
ENG
Soggetto:
CRYSTAL-STRUCTURE; TI(BH4)3(PME3)2;
Tipo documento:
Note
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Science Citation Index Expanded
Citazioni:
17
Recensione:
Indirizzi per estratti:
Citazione:
S.C.P. Joseph et al., "NOVEL ZIRCONIUM BOROHYDRIDE COMPLEXES - SYNTHESES AND MOLECULAR-STRUCTURES OF [ZR(ETA-C8H6(SIME(3))(2))(ETA(3)-BH4)(ETA(2)-BH4)] AND TA(6)ETA(4)-C8H6(SIME(3))(2))(MU-H)ZR(ETA(3)-BH4)]", Organometallics, 14(7), 1995, pp. 3566-3569

Abstract

The reaction between the dimer [{Zr(COT'')-Cl-2}(2)] (COT'' = 1,4-bis(trimethylsilyl)cyclooctatetraene) and [LiBH4] affords crystallographically characterized Zr(eta-C8H6(SiMe(3))(2))(eta(3)-BH4)(eta(2)-BH4)]. The latter reacts with Lewis bases to afford (6):eta(4)-C8H6(SiMe(3))(2))(mu-H)Zr(eta(3)-BH4)], whose X-ray structure reveals a novel bridging mode for one of the COT'' ligands.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 29/11/20 alle ore 03:30:07