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Titolo:
ISOLATION AND STRUCTURE ELUCIDATION OF LOLILLINE, A POSSIBLE BIOSYNTHETIC PRECURSOR OF THE LOLITREM FAMILY OF TREMORGENIC MYCOTOXINS
Autore:
MUNDAYFINCH SC; WILKINS AL; MILES CO; TOMODA H; OMURA S;
Indirizzi:
RUAKURA AGR RES CTR,NEW ZEALAND PASTORAL AGR RES INST LTD,PRIVATE BAG3123 HAMILTON NEW ZEALAND RUAKURA AGR RES CTR,NEW ZEALAND PASTORAL AGR RES INST LTD HAMILTON NEW ZEALAND UNIV WAIKATO,DEPT CHEM HAMILTON NEW ZEALAND KITASATO INST,MINATO KU TOKYO 108 JAPAN
Titolo Testata:
Journal of agricultural and food chemistry
fascicolo: 1, volume: 45, anno: 1997,
pagine: 199 - 204
SICI:
0021-8561(1997)45:1<199:IASEOL>2.0.ZU;2-R
Fonte:
ISI
Lingua:
ENG
Soggetto:
ACREMONIUM-LOLII; EMERICELLA-STRIATA; RYEGRASS STAGGERS; FUNGAL PRODUCTS; PAXILLINE; METABOLITES; NEUROTOXINS; INDOLODITERPENES; TRANSFORMATION; ENDOPHYTE;
Keywords:
ACREMONIUM LOLII; LOLIUM PERENNE; ENDOPHYTE; LOLITREM; PAXILLINE; TERPENDOLE; TREMOR; RYEGRASS STAGGERS; NEUROTOXIN; MYCOTOXIN; BIOSYNTHESIS;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Science Citation Index Expanded
Science Citation Index Expanded
Citazioni:
37
Recensione:
Indirizzi per estratti:
Citazione:
S.C. Mundayfinch et al., "ISOLATION AND STRUCTURE ELUCIDATION OF LOLILLINE, A POSSIBLE BIOSYNTHETIC PRECURSOR OF THE LOLITREM FAMILY OF TREMORGENIC MYCOTOXINS", Journal of agricultural and food chemistry, 45(1), 1997, pp. 199-204

Abstract

Lolilline (1), a new indole-diterpenoid, was isolated from extracts of the seed of Lolium perenne infected with the endophytic fungus Acremonium lolii. Lolilline contained structural features present in both the lolitrem mycotoxins and the simpler indole-diterpenoid tremorgen paxilline, suggesting that lolilline may be an intermediate in the biosynthesis of the lolitrems from the presumed precursor paxilline. Although paxilline, terpendole C, and lolitrem B were found to be tremorgenic, lolilline was not, providing new insight into structure-activity relationships within the indole-diterpenoids.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 12/07/20 alle ore 03:25:26