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Titolo:
[3,9-DIMETHYL-4,8-DIAZA-3,8-UNDECADIENE-2,10-DIONE DIOXIMATO(1-)](THIOCYANATO)-COPPER(II) AND 9-TETRAMETHYL-4,8-DIAZA-3,8-UNDECADIENE-2,10-DIONE DIOXIMATO(1-)](ISOTHIOCYANATO)COPPER(II)
Autore:
TAHIROV TH; LU TH; LUH H; LAI CY; CHUNG CS;
Indirizzi:
NATL TSING HUA UNIV,DEPT PHYS HSINCHU 300 TAIWAN CHUNG CHENG INST TECHNOL,DEPT APPL CHEM TAYUAN 335 TAIWAN NATL TSING HUA UNIV,DEPT CHEM HSINCHU 300 TAIWAN
Titolo Testata:
Acta crystallographica. Section C, Crystal structure communications
, volume: 51, anno: 1995,
parte:, 5
pagine: 846 - 849
SICI:
0108-2701(1995)51:<846:[D>2.0.ZU;2-O
Fonte:
ISI
Lingua:
ENG
Soggetto:
NICKEL(II) COMPLEX; DEPROTONATED ANION; DIOXIME;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
10
Recensione:
Indirizzi per estratti:
Citazione:
T.H. Tahirov et al., "[3,9-DIMETHYL-4,8-DIAZA-3,8-UNDECADIENE-2,10-DIONE DIOXIMATO(1-)](THIOCYANATO)-COPPER(II) AND 9-TETRAMETHYL-4,8-DIAZA-3,8-UNDECADIENE-2,10-DIONE DIOXIMATO(1-)](ISOTHIOCYANATO)COPPER(II)", Acta crystallographica. Section C, Crystal structure communications, 51, 1995, pp. 846-849

Abstract

The coordination geometries about the Cu-II ions in both [3,9-dimethyl-4,8 -diaza-3,8-undecadiene-2,10-dione dioximato(1 -)](thiocyanato)copper(II), [Cu(C-11-H19N4O2)(SCN)] (1) and [3,6,6,9-tetramethyl-4,8 -diaza-3,8-undecadiene-2,10-dione dioximato(1 -)](isothiocyanato)copper(II), [CU(C13H23N4O2)(NCS)] (2), are distorted square pyramidal with thefour diazadioxime N atoms in equatorial positions and the monodentateligand axial. This monodentate axial ligand is an S-bonded thiocyanato group in complex (1) and an N-bonded isothiocyanato group in (2). The intramolecular O O hydrogen-bond lengths are 2.530(4) and 2.490(2) Angstrom in complexes (1) and (2), respectively.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 14/07/20 alle ore 19:44:29