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Titolo:
PORPHYRIN ANALOGS OF TROGERS BASE - LARGE CHIRAL CAVITIES WITH A BIMETALLIC BINDING-SITE
Autore:
CROSSLEY MJ; HAMBLEY TW; MACKAY LG; TRY AC; WALTON R;
Indirizzi:
UNIV SYDNEY,SCH CHEM SYDNEY NSW 2006 AUSTRALIA
Titolo Testata:
Journal of the Chemical Society, Chemical Communications
fascicolo: 10, , anno: 1995,
pagine: 1077 - 1079
SICI:
0022-4936(1995):10<1077:PAOTB->2.0.ZU;2-K
Fonte:
ISI
Lingua:
ENG
Soggetto:
SYNTHETIC HOST; RECOGNITION; MODEL; 1,10-PHENANTHROLINE; CHEMISTRY;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
24
Recensione:
Indirizzi per estratti:
Citazione:
M.J. Crossley et al., "PORPHYRIN ANALOGS OF TROGERS BASE - LARGE CHIRAL CAVITIES WITH A BIMETALLIC BINDING-SITE", Journal of the Chemical Society, Chemical Communications, (10), 1995, pp. 1077-1079

Abstract

2-Amino-5,10,15,20-tetraarylporphyrins react with formaldehyde to give good yields of the corresponding octaaryl derivatives of the Troger's base analogue in which two porphyrins are covalently linked by a diazocine bridge; the X-ray crystal structure of the bis(tetraphenylporphyrinato)dipaliadium(II) derivative 6 reveals a concave chiral cavity with two metal ion binding sites suitable for ditopic interactions withguest molecules.

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Documento generato il 22/10/20 alle ore 09:16:56