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Titolo:
SYNTHESIS, PROPERTIES AND STRUCTURE OF SOME LANTHANIDE NITRATE BINUCLEAR COMPLEX WITH N,N,N',N'-TETRABUTYLADIPAMIDE (4)CONBU(2))(BU(2)NCO(CH2)(4)CONBU(2))(2)(NO3)(6)]
Autore:
WANG HZ; ZHAO SX; QIAN P; DAI J; CAO ZB; YU KB;
Indirizzi:
SUZHOU UNIV,DEPT CHEM SUZHOU 215006 PEOPLES R CHINA ACAD SINICA,CHENGDU CTR ANAL & MEASUREMENT CHENGDU 610041 PEOPLES R CHINA
Titolo Testata:
Polyhedron
fascicolo: 3, volume: 14, anno: 1995,
pagine: 407 - 412
SICI:
0277-5387(1995)14:3<407:SPASOS>2.0.ZU;2-B
Fonte:
ISI
Lingua:
ENG
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Science Citation Index Expanded
Citazioni:
7
Recensione:
Indirizzi per estratti:
Citazione:
H.Z. Wang et al., "SYNTHESIS, PROPERTIES AND STRUCTURE OF SOME LANTHANIDE NITRATE BINUCLEAR COMPLEX WITH N,N,N',N'-TETRABUTYLADIPAMIDE (4)CONBU(2))(BU(2)NCO(CH2)(4)CONBU(2))(2)(NO3)(6)]", Polyhedron, 14(3), 1995, pp. 407-412

Abstract

Some lanthanide nitrate complexes with N,N,N',N'-tetrabutyladipamide (TBAA) have been prepared. These complexes with the general formula [Ln(2) mu-(TBAA) (TBAA)(2)(NO3)(6)] have been characterized by means of elemental analysis, IR spectra and conductance measurement. The crystal and molecular structure of [Gd-2 mu-(TBAA) (TBAA)(2)(NO3)(6)] has been determined by single-crystal X-ray diffraction. This complex contains a binuclear molecule with three organic ligands. Two carbonyls of one organic ligand join two Gd(III) and each Gd(III) is coordinated through two carbonyls of one organic ligand. The six nitrates are all bidentate. Each Gd(III) is coordinated by nine oxygen atoms which form a distorted tricapped trigonal prism.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 03/12/20 alle ore 21:46:24