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Titolo:
ENANTIOSELECTIVE SYNTHESIS OF MACROLIDE PHEROMONES, (5Z,13S)-5-TETRADECEN-13-OLIDE AND (9R)-DECAN-9-OLIDE, BY USING MN-SALEN CATALYZED ASYMMETRIC EPOXIDATION AS A KEY STEP
Autore:
HAMADA T; DAIKAI K; IRIE R; KATSUKI T;
Indirizzi:
KYUSHU UNIV 33,FAC SCI,DEPT CHEM,HIGASHI KU FUKUOKA 812 JAPAN KYUSHU UNIV 33,FAC SCI,DEPT CHEM,HIGASHI KU FUKUOKA 812 JAPAN
Titolo Testata:
Synlett
fascicolo: 5, , anno: 1995,
pagine: 407 - 408
SICI:
0936-5214(1995):5<407:ESOMP(>2.0.ZU;2-B
Fonte:
ISI
Lingua:
ENG
Soggetto:
FLAT GRAIN BEETLE; CRYPTOLESTES-PUSILLUS SCHONHERR; AGGREGATION PHEROMONES; PHORACANTHA-SYNONYMA; COLEOPTERA; SECRETION; LONGICORN;
Keywords:
(SALEN)MANGANESE(III) COMPLEX; ASYMMETRIC EPOXIDATION; ENYNE; HOMOPROPARGYLIC ALCOHOL; MACROLIDE PHEROMONE;
Tipo documento:
Note
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
15
Recensione:
Indirizzi per estratti:
Citazione:
T. Hamada et al., "ENANTIOSELECTIVE SYNTHESIS OF MACROLIDE PHEROMONES, (5Z,13S)-5-TETRADECEN-13-OLIDE AND (9R)-DECAN-9-OLIDE, BY USING MN-SALEN CATALYZED ASYMMETRIC EPOXIDATION AS A KEY STEP", Synlett, (5), 1995, pp. 407-408

Abstract

Highly enantioselective epoxidation of cis-enynes catalyzed by the newly developed Mn-salen catalyst 1 and subsequent LAH reduction provided optically active homopropargylic alcohols which served as useful building blocks for the synthesis of various pheromones. For example, (5Z, 13S)-5-tetradecen-13-olide and (9R)-decan-9-olide were synthesized from cis-enynes in a straightforward manner by using asymmetric epoxidation as a key step.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 14/07/20 alle ore 09:43:22