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Titolo: ENZYMATIC RESOLUTION OF 1-FERROCENYLETHANOL AND 1-FERROCENYL-2,2,2-TRIFLUOROETHANOL USING LIPASES
Autore: IZUMI T; ARATANI S;
- Indirizzi:
- YAMAGATA UNIV,FAC ENGN,DEPT MAT SCI & ENGN YONEZAWA YAMAGATA 992 JAPAN
- Titolo Testata:
- Journal of chemical technology and biotechnology
fascicolo: 1,
volume: 63,
anno: 1995,
pagine: 25 - 32
- SICI:
- 0268-2575(1995)63:1<25:ERO1A1>2.0.ZU;2-A
- Fonte:
- ISI
- Lingua:
- ENG
- Soggetto:
- KINETIC RESOLUTION; DERIVATIVES; ALCOHOLS; ORGANOMETALLICS;
- Keywords:
- 1-FERROCENYLETHANOL; 1-FERROCENYL-2,2,2-TRIFLUOROETHANOL; PSEUDOMONAS CEPACIA LIPASE; CANDIA CYCLINDRACEA LIPASE; LIPASE FROM CANDIDA RUGOSA; PORCINE PANCREATIC LIPASE; PIG LIVER ESTERASE;
- Tipo documento:
- Article
- Natura:
- Periodico
- Settore Disciplinare:
- Science Citation Index Expanded
- Science Citation Index Expanded
- Science Citation Index Expanded
- Citazioni:
- 19
- Recensione:
- Indirizzi per estratti:
-
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- Citazione:
- T. Izumi e S. Aratani, "ENZYMATIC RESOLUTION OF 1-FERROCENYLETHANOL AND 1-FERROCENYL-2,2,2-TRIFLUOROETHANOL USING LIPASES", Journal of chemical technology and biotechnology, 63(1), 1995, pp. 25-32
Abstract
1-Ferrocenylethanol and 1-ferrocenyl-2,2,2-trifluoroethanol were resolved with transesterification by lipases to the optically active (R)-esters and (S)-alcohols. Enzymatic hydrolysis of the racemic esters of 1-ferrocenylethanol using lipases yielded (R)-alcohol and (S)-esters. Enantioselective hydrolysis of racemic acetate or butanoate of 1-ferrocenyl-2,2,2-trifluoroethanol yielded the (S)-alcohol and (R)-esters. Enzymatic hydrolysis of (+/-)-acetate of 1-ferrocenyl-2, 2,2-trifluoroethanol yielded (R)-alcohol and (S)-acetate, but the equivalent (+/-)-butanoate was not hydrolyzed.
ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 23/01/21 alle ore 10:18:51