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Titolo:
ENZYMATIC RESOLUTION OF 1-FERROCENYLETHANOL AND 1-FERROCENYL-2,2,2-TRIFLUOROETHANOL USING LIPASES
Autore:
IZUMI T; ARATANI S;
Indirizzi:
YAMAGATA UNIV,FAC ENGN,DEPT MAT SCI & ENGN YONEZAWA YAMAGATA 992 JAPAN
Titolo Testata:
Journal of chemical technology and biotechnology
fascicolo: 1, volume: 63, anno: 1995,
pagine: 25 - 32
SICI:
0268-2575(1995)63:1<25:ERO1A1>2.0.ZU;2-A
Fonte:
ISI
Lingua:
ENG
Soggetto:
KINETIC RESOLUTION; DERIVATIVES; ALCOHOLS; ORGANOMETALLICS;
Keywords:
1-FERROCENYLETHANOL; 1-FERROCENYL-2,2,2-TRIFLUOROETHANOL; PSEUDOMONAS CEPACIA LIPASE; CANDIA CYCLINDRACEA LIPASE; LIPASE FROM CANDIDA RUGOSA; PORCINE PANCREATIC LIPASE; PIG LIVER ESTERASE;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Science Citation Index Expanded
Science Citation Index Expanded
Citazioni:
19
Recensione:
Indirizzi per estratti:
Citazione:
T. Izumi e S. Aratani, "ENZYMATIC RESOLUTION OF 1-FERROCENYLETHANOL AND 1-FERROCENYL-2,2,2-TRIFLUOROETHANOL USING LIPASES", Journal of chemical technology and biotechnology, 63(1), 1995, pp. 25-32

Abstract

1-Ferrocenylethanol and 1-ferrocenyl-2,2,2-trifluoroethanol were resolved with transesterification by lipases to the optically active (R)-esters and (S)-alcohols. Enzymatic hydrolysis of the racemic esters of 1-ferrocenylethanol using lipases yielded (R)-alcohol and (S)-esters. Enantioselective hydrolysis of racemic acetate or butanoate of 1-ferrocenyl-2,2,2-trifluoroethanol yielded the (S)-alcohol and (R)-esters. Enzymatic hydrolysis of (+/-)-acetate of 1-ferrocenyl-2, 2,2-trifluoroethanol yielded (R)-alcohol and (S)-acetate, but the equivalent (+/-)-butanoate was not hydrolyzed.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 28/11/20 alle ore 00:34:33