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Titolo:
KINETIC-STUDIES ON THE REACTION OF THE HETEROBIMETALLIC ANION, (OC)(5)CRMN(CO)(5)(-)M(+) (M(+)=NA+, PPN+) WITH ALLYL BROMIDE
Autore:
PARK YK; KIM GS; SONG GO;
Indirizzi:
KANGWEON NATL UNIV,DEPT SCI EDUC CHUNCHON 200701 SOUTH KOREA KANGWEON NATL UNIV,DEPT CHEM CHUNCHON 200701 SOUTH KOREA
Titolo Testata:
Bulletin of the Korean Chemical Society
fascicolo: 4, volume: 16, anno: 1995,
pagine: 310 - 315
SICI:
0253-2964(1995)16:4<310:KOTROT>2.0.ZU;2-V
Fonte:
ISI
Lingua:
ENG
Soggetto:
METAL METAL BONDS; MOLECULAR-STRUCTURE; ; COMPLEXES; MANGANESE; CO; COMPOUND; CLEAVAGE; HYDRIDES; CRYSTAL;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
43
Recensione:
Indirizzi per estratti:
Citazione:
Y.K. Park et al., "KINETIC-STUDIES ON THE REACTION OF THE HETEROBIMETALLIC ANION, (OC)(5)CRMN(CO)(5)(-)M(+) (M(+)=NA+, PPN+) WITH ALLYL BROMIDE", Bulletin of the Korean Chemical Society, 16(4), 1995, pp. 310-315

Abstract

The heterobimetallic anion, (OC)(5)CrMn(CO)(5)(-)M(+) (M(+)=Na+, PPN+), which has a donor-acceptor metal-metal bond,(1) was reacted with allyl bromide to yield BrCr(CO)(5)(-) and Mn(CO)(5)(CH2CHCH2). The reaction mechanism has been proposed in terms of the consecutive reaction pathway in which Cr(CO)(5)(THF) is an important intermediate leading tothe corresponding product. Counterion effect on this reaction was also evaluated and the results were compared with those of the corresponding reaction of the mononuclear carbonyl anion, Mn(CO)(5)(-).

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Documento generato il 09/07/20 alle ore 20:38:14