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Titolo:
SMALL RINGS .88. REACTIONS OF TETRA-TERT- BUTYLTETRAHEDRANE - OXIDATION TO THE RADICAL-CATION AS THE FIRST STEP
Autore:
MAIER G; RANG H; EMRICH R; GRIES S; IRNGARTINGER H;
Indirizzi:
UNIV GIESSEN,INST ORGAN CHEM,HEINRICH BUFF RING 58 D-35392 GIESSEN GERMANY UNIV HEIDELBERG,INST ORGAN CHEM D-69120 HEIDELBERG GERMANY
Titolo Testata:
Liebigs Annalen
fascicolo: 1, , anno: 1995,
pagine: 161 - 167
SICI:
0947-3440(1995):1<161:SR.ROT>2.0.ZU;2-M
Fonte:
ISI
Lingua:
GER
Soggetto:
CHARGE-TRANSFER COMPLEXES; TETRAHEDRANE; IONS; BUTYLCYCLOBUTADIENE; CYCLOBUTADIENE; REARRANGEMENT; KETENIMINES; OXYGENATION; ALKENES; OXETENE;
Keywords:
HALOGEN ADDITION; AUTOXIDATION; REDOX CHEMISTRY; OXETES, STABLE;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
51
Recensione:
Indirizzi per estratti:
Citazione:
G. Maier et al., "SMALL RINGS .88. REACTIONS OF TETRA-TERT- BUTYLTETRAHEDRANE - OXIDATION TO THE RADICAL-CATION AS THE FIRST STEP", Liebigs Annalen, (1), 1995, pp. 161-167

Abstract

The chemistry of tetrahedrane 1 and cyclobutadiene 3 is governed by the initial formation of radical cation 2. In spite of the high steric hindrance 2 cannot be isolated as a radical-ion pair. Reaction of 3 with O-2 generates the oxete 21 which is surprisingly stable (up to 200 degrees C).

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 28/11/20 alle ore 00:15:25