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Titolo:
SYNTHESIS AND STRUCTURE OF MU-TETRABUTYLA DIPAMIDE LANTHANIUM(III) BINUCLEAR COMPLEX )(4)CONBU(2)][BU(2)NCO(CH2)(4)CONBU(2)](2)(NO3)(6)
Autore:
WANG HZ; ZHAO SX; CUI L; QIAN P; CAO ZB;
Indirizzi:
SUZHOU UNIV,DEPT CHEM SUZHOU 215006 PEOPLES R CHINA CHINESE ACAD SCI,CHENGDU CTR ANAL & DETERMINAT CHENGDU 610041 PEOPLESR CHINA
Titolo Testata:
Huaxue xuebao
fascicolo: 2, volume: 53, anno: 1995,
pagine: 141 - 146
SICI:
0567-7351(1995)53:2<141:SASOMD>2.0.ZU;2-B
Fonte:
ISI
Lingua:
CHI
Soggetto:
DONOR LIGANDS;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
6
Recensione:
Indirizzi per estratti:
Citazione:
H.Z. Wang et al., "SYNTHESIS AND STRUCTURE OF MU-TETRABUTYLA DIPAMIDE LANTHANIUM(III) BINUCLEAR COMPLEX )(4)CONBU(2)][BU(2)NCO(CH2)(4)CONBU(2)](2)(NO3)(6)", Huaxue xuebao, 53(2), 1995, pp. 141-146

Abstract

The complex La-2 H2)(4)CONBu(2)][Bu(2)NCO(CH2)(4)CONBu(2)](2)(NO3)( )6 has been synthesized. The crystal structure of title complex was established by a single-crystal X-ray diffraction study and described as follows: triclinic space group P ($) over bar 1, a = 1.4693(2), b = 1.5882(3), c = 1.9916(4)nm, alpha = 90.92(2), beta = 92.93(1), gamma = 103.73(1)degrees, V = 4.507(1)nm(3), D-c = 1.29g . cm(-3), Final R value is 0.0738. This complex has binuclear molecule with three organic ligand molecules. Two carbonyls of one organic ligand join two La (III),in addition each La(III) is coordinated through two carbonyls of one organic ligand, six nitrates are all bidentate ligands. Each La(III) is coordinated by nine oxygen atoms which form a distorted tricapped trigonal prism.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 29/11/20 alle ore 10:05:36